First example of dendrons as topological amplifiers

被引：11

作者：

Turrin, Cedric-Olivier ^{[1
]}

Maraval, Alexandrine ^{[1
]}

Magro, Germinal ^{[1
]}

Maraval, Valerie ^{[1
]}

Caminade, Anne-Marie ^{[1
]}

Majoral, Jean-Pierre ^{[1
]}

机构：

[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse 4, France

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2006年 / 13期

关键词：

dendrons; dendrimers; macrocycles; phosphorus; NMR spectroscopy;

D O I：

10.1002/ejic.200600217

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A phosphorus-containing dendron was synthesized and grafted to a tetraphosphorus macrocycle. The presence of such bulky substituents allowed for the first time the amplification of topological differences in the macrocycle. These differences become detectable by P-31 NMR spectroscopy, with the appearance of several signals for the phosphorus atoms included in the macrocycle.

引用

页码：2556 / 2560

页数：5

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