A novel simple and efficient bromination protocol for activated arenes

被引：23
|
作者：
Tsoukala, Anna [1 ]
Liguori, Lucia [2 ]
Occhipinti, Giovanni [1 ]
Bjorsvika, Hans-Rene [1 ]
机构：
[1] Univ Bergen, Dept Chem, N-5007 Bergen, Norway
[2] Fluens Synth AS, N-5008 Bergen, Norway
来源：
TETRAHEDRON LETTERS | 2009年 / 50卷 / 07期
关键词：
Bromination; Oxidation; Redox; Chemoselectivity; Green chemistry; Electrophilic substitution; ALKYL PHENYL ETHERS; AROMATIC-COMPOUNDS; POTASSIUM-BROMIDE; METAL BROMIDES; MONOBROMINATION; HALOGENATION; MECHANISM; OXONE(R); SOLVENT; HALIDE;
D O I：
10.1016/j.tetlet.2008.12.016
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient, high yielding, and environmentally benign bromination using an alkali metal bromide as the bromine source is disclosed. Investigation of the protocol revealed that the method operates for activated arenes producing the corresponding monobrominated products in good to excellent yields. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码：831 / 833
页数：3
相关论文
共 50 条
  • [21] Polystyrene supported bromoderivative of 2-oxazolidone - an efficient reagent for microwave assisted bromination reactions
    Mathew, Anjaly
    Mathew, Beena
    Koshy, Ebey P.
    JOURNAL OF POLYMER RESEARCH, 2020, 27 (09)
  • [22] Oxidative umpolung selenocyanation of ketones and arenes: An efficient protocol to the synthesis of selenocyanates
    Cui, Jianguo
    Wei, Meizhen
    Pang, Liping
    Xiao, JunAn
    Gan, Chunfang
    Guo, Jiali
    Xie, Chuanfang
    Zhu, Qiming
    Huang, Yanmin
    TETRAHEDRON, 2020, 76 (10)
  • [23] Fast and Efficient Bromination of Aromatic Compounds with Ammonium Bromide and Oxone
    Naresh, Mameda
    Kumar, Macharla Arun
    Reddy, Marri Mahender
    Swamy, Peraka
    Nanubolu, Jagadeesh Babu
    Narender, Nama
    SYNTHESIS-STUTTGART, 2013, 45 (11): : 1497 - 1504
  • [24] A Oxidative Bromination of (Hetero) Arenes in the TMSBr/DMSO System: A Non-Aqueous Procedure Facilitates Synthetic Strategies
    Kajita, Harutake
    Togni, Antonio
    CHEMISTRYSELECT, 2017, 2 (03): : 1117 - 1121
  • [25] Sulfated polyborate catalyzed rapid and efficient electrophilic thiocyanation of activated arenes
    Patil, Nilesh B.
    Chaturbhuj, Ganesh U.
    TETRAHEDRON LETTERS, 2022, 96
  • [26] Stepwise Mechanism for the Bromination of Arenes by a Hypervalent Iodine Reagent
    Granados, Albert
    Shafir, Alexandr
    Arrieta, Ana
    Cossio, Fernando P.
    Vallribera, Adelina
    JOURNAL OF ORGANIC CHEMISTRY, 2020, 85 (04): : 2142 - 2150
  • [27] An efficient and selective method for the iodination and bromination of alcohols under mild conditions
    Khazdooz, Leila
    Zarei, Amin
    Aghaei, Hamidreza
    Azizi, Ghobad
    Gheisari, Mohammad Mehdi
    TETRAHEDRON LETTERS, 2016, 57 (02) : 168 - 171
  • [28] Introduction of efficient catalytic system for the regioselective aerobic bromination of aromatic compounds
    Dehkordi, S. Saeid Saei
    Jafari, Abbas Ali
    Albadi, Jalal
    Samimi, Heshmat Allah
    SYNTHETIC COMMUNICATIONS, 2022, 52 (21) : 2048 - 2056
  • [29] Amphiphilic Indoles as Efficient Phase-Transfer Catalysts for Bromination in Water
    Zhang, Qingyu
    Xu, Yongyuan
    Liang, Xiaochen
    Ke, Zhihai
    CHEMSUSCHEM, 2022, 15 (12)
  • [30] Directed meta-Selective Bromination of Arenes with Ruthenium Catalysts
    Yu, Qingzhen
    Hu, Le'an
    Wang, Yue
    Zheng, Shasha
    Huang, Jianhui
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (50) : 15284 - 15288
12345