Half-sandwich ruthenium(II) complexes with water-soluble Schiff base ligands: Synthesis and catalytic activity in transfer hydrogenation of carbonyl compounds

被引：15
作者：
Talouki, Somayeh Azizi [1 ]
Grivani, Gholamhossein [1 ]
Crochet, Pascale [2 ]
Cadierno, Victorio [2 ]
机构：
[1] Damghan Univ, Sch Chem, Damghan 36715364, Iran
[2] Univ Oviedo, Inst Univ Quim Organometal Enrique Moles, Dept Quim Organ & Inorgan,Lab Compuestos Organome, Ctr Innovac Quim Avanzada ORFEO CINQA, E-33006 Oviedo, Spain
来源：
INORGANICA CHIMICA ACTA | 2017年 / 456卷
关键词：
Schiff-base ligands; Ionic ligands; Ruthenium; Transfer hydrogenation; Ketones; Aqueous catalysis; ASYMMETRIC TRANSFER HYDROGENATION; METAL-COMPLEXES; HYDRATION REACTIONS; ANTICANCER ACTIVITY; CRYSTAL-STRUCTURE; IMIDAZOLIUM SALT; ARENE COMPLEXES; BOND FORMATION; IONIC LIQUIDS; DNA-BINDING;
D O I：
10.1016/j.ica.2016.10.041
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New ionic Schiff-base ligands have been synthesized by condensation of (3-formyl-4-hydroxybenzyl) triphenylphosphonium and 3-(3-formyl-4-hydroxybenzyl)-1-methyl-1H-imidazol-3-ium chloride and hexafluorophosphate salts with N,N-dimethylethylenediamine. Treatment of the dimeric derivative [{RuCl(mu-Cl)(eta(6)-p-cymene)}2] with two equivalents of these ligands allowed the preparation of novel mononuclear water-soluble Ru(II) complexes, which proved to be catalytically active in the transfer hydrogenation of ketones and aldehydes under aqueous conditions. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码：142 / 148
页数：7
相关论文
共 50 条
  • [31] Half-sandwich ruthenium(II) complexes containing O, N bidentate azo ligands: Synthesis, structure and their catalytic activity towards one-pot conversion of aldehydes to primary amides and transfer hydrogenation of ketones
    Nandhini, Raja
    Venkatachalam, Galmari
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2019, 895 : 15 - 22
  • [32] Synthesis and characterization of half-sandwich ruthenium(II) complexes with N-alkyl pyridyl-imine ligands and their application in transfer hydrogenation of ketones
    Joel M. Gichumbi
    Holger B. Friedrich
    Bernard Omondi
    Transition Metal Chemistry, 2016, 41 : 867 - 877
  • [33] Synthesis, structural characterization, electrochemistry and catalytic transfer hydrogenation of ruthenium(II) carbonyl complexes containing tridentate benzoylhydrazone ligands
    Prabhu, Rupesh Narayana
    Ramesh, Rengan
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2012, 718 : 43 - 51
  • [34] A mechanistic study of transfer hydrogenation catalyzed by cyclometallated ruthenium half-sandwich complexes
    Reshi, Noor U. Din
    Senthurpandi, Dineshchakravarthy
    Samuelson, Ashoka G.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2018, 866 : 189 - 199
  • [35] Diastereomeric half-sandwich Ru(II) cationic complexes containing amino amide ligands. Synthesis, solution properties, crystal structure and catalytic activity in transfer hydrogenation of acetophenone
    Bacchi, Alessia
    Pelagatti, Paolo
    Pelizzi, Corrado
    Rogolino, Dominga
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (19) : 3200 - 3211
  • [36] Ruthenium(II)-catalyzed transfer hydrogenation of aldehydes with new water-soluble monotosylated ethylenediamines as ligands
    Huo, Hengrui
    Zhou, Zhongqiang
    Zhang, Aiqing
    Wu, Lamei
    RESEARCH ON CHEMICAL INTERMEDIATES, 2012, 38 (01) : 261 - 268
  • [37] The Synthesis, Structure, and H/D Exchange Reactions of Water-Soluble Half-Sandwich Ruthenium(II) Hydrides of Indenyl and Dihydropentalenyl
    Lanorio, Jocelyn P.
    Mebi, Charles A.
    Frost, Brian J.
    ORGANOMETALLICS, 2019, 38 (09) : 2031 - 2041
  • [38] Half-Sandwich Ruthenium Phenolate-Oxazoline Complexes: Experimental and Theoretical Studies in Catalytic Transfer Hydrogenation of Nitroarene
    Jia, Wei-Guo
    Ling, Shuo
    Zhang, Hai-Ning
    Sheng, En-Hong
    Lee, Richmond
    ORGANOMETALLICS, 2018, 37 (01) : 40 - 47
  • [39] Half-Sandwich Iridium(III) and Ruthenium(II) Complexes Containing PP-Chelating Ligands
    Li, JuanJuan
    Tian, Meng
    Tian, Zhenzhen
    Zhang, Shumiao
    Yan, Chao
    Shao, Changfang
    Liu, Zhe
    INORGANIC CHEMISTRY, 2018, 57 (04) : 1705 - 1716
  • [40] Ruthenium(II) complexes with pyridine-based Schiff base ligands: Synthesis, structural characterization and catalytic hydrogenation of ketones
    Buldurun, Kenan
    Ozdemir, Metin
    JOURNAL OF MOLECULAR STRUCTURE, 2020, 1202
12345