Half-sandwich ruthenium(II) complexes with water-soluble Schiff base ligands: Synthesis and catalytic activity in transfer hydrogenation of carbonyl compounds

被引：15
|
作者：
Talouki, Somayeh Azizi [1 ]
Grivani, Gholamhossein [1 ]
Crochet, Pascale [2 ]
Cadierno, Victorio [2 ]
机构：
[1] Damghan Univ, Sch Chem, Damghan 36715364, Iran
[2] Univ Oviedo, Inst Univ Quim Organometal Enrique Moles, Dept Quim Organ & Inorgan,Lab Compuestos Organome, Ctr Innovac Quim Avanzada ORFEO CINQA, E-33006 Oviedo, Spain
来源：
INORGANICA CHIMICA ACTA | 2017年 / 456卷
关键词：
Schiff-base ligands; Ionic ligands; Ruthenium; Transfer hydrogenation; Ketones; Aqueous catalysis; ASYMMETRIC TRANSFER HYDROGENATION; METAL-COMPLEXES; HYDRATION REACTIONS; ANTICANCER ACTIVITY; CRYSTAL-STRUCTURE; IMIDAZOLIUM SALT; ARENE COMPLEXES; BOND FORMATION; IONIC LIQUIDS; DNA-BINDING;
D O I：
10.1016/j.ica.2016.10.041
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New ionic Schiff-base ligands have been synthesized by condensation of (3-formyl-4-hydroxybenzyl) triphenylphosphonium and 3-(3-formyl-4-hydroxybenzyl)-1-methyl-1H-imidazol-3-ium chloride and hexafluorophosphate salts with N,N-dimethylethylenediamine. Treatment of the dimeric derivative [{RuCl(mu-Cl)(eta(6)-p-cymene)}2] with two equivalents of these ligands allowed the preparation of novel mononuclear water-soluble Ru(II) complexes, which proved to be catalytically active in the transfer hydrogenation of ketones and aldehydes under aqueous conditions. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码：142 / 148
页数：7
相关论文
共 50 条
  • [21] Synthesis of half-sandwich ruthenium(II) and iridium(III) complexes containing imidazole-based phosphinite ligands and their use in catalytic transfer hydrogenation of acetophenone with isopropanol
    Isik, Ugur
    Meric, Nermin
    Kayan, Cezmi
    Kilic, Ahmet
    Belyankova, Yelizaveta
    Zazybin, Alexey
    Aydemir, Murat
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2023, 998
  • [22] Cationic half-sandwich ruthenium (II) complexes ligated by pyridyl-triazole ligands: Transfer hydrogenation and mechanistic studies
    Joseph, M. C.
    Swarts, A. J.
    Mapolie, S. F.
    POLYHEDRON, 2022, 212
  • [23] Seleno-Nucleobases and Their Water-Soluble Ruthenium-Arene Half-Sandwich Complexes: Chemistry and Biological Activity
    Mitra, Raja
    Pramanik, Anup K.
    Samuelson, Ashoka G.
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2014, (33) : 5733 - 5740
  • [24] Ruthenium(II) pentamethylcyclopentadienyl half-sandwich carbene complexes with polypyridyl ligands
    Albertin, Gabriele
    Antoniutti, Stefano
    Bortoluzzi, Marco
    Castro, Jesus
    Trevisan, Mauro
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2017, 848 : 1 - 9
  • [25] Chemoselective and efficient catalytic hydrogenation of furfural by iridium and ruthenium half-sandwich complexes
    Oklu, Novisi K.
    Makhubela, Banothile C. E.
    NEW JOURNAL OF CHEMISTRY, 2020, 44 (22) : 9382 - 9390
  • [26] Synthesis and characterization of half-sandwich ruthenium(II) complexes with N-alkyl pyridyl-imine ligands and their application in transfer hydrogenation of ketones
    Gichumbi, Joel M.
    Friedrich, Holger B.
    Omondi, Bernard
    TRANSITION METAL CHEMISTRY, 2016, 41 (08) : 867 - 877
  • [27] Synthesis and characterization of half-sandwich ruthenium(II) complexes with N-alkyl pyridyl-imine ligands and their application in transfer hydrogenation of ketones
    Joel M. Gichumbi
    Holger B. Friedrich
    Bernard Omondi
    Transition Metal Chemistry, 2016, 41 : 867 - 877
  • [28] Transfer hydrogenation of ketones catalysed by half-sandwich (η6-p-cymene) ruthenium(II) complexes incorporating benzoylhydrazone ligands
    Mohan, Nanjan
    Ramesh, Rengan
    APPLIED ORGANOMETALLIC CHEMISTRY, 2017, 31 (07)
  • [29] A mechanistic study of transfer hydrogenation catalyzed by cyclometallated ruthenium half-sandwich complexes
    Reshi, Noor U. Din
    Senthurpandi, Dineshchakravarthy
    Samuelson, Ashoka G.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2018, 866 : 189 - 199
  • [30] Half-Sandwich Ru(II) Complexes with N,O-Chelate Ligands: Diverse Catalytic Activity for Amine Synthesis in Water
    Yun, Xue-Jing
    Ling, Chun
    Deng, Wei
    Liu, Zhen-Jiang
    Yao, Zi-Jian
    ORGANOMETALLICS, 2020, 39 (21) : 3830 - 3838
12345