Half-sandwich ruthenium(II) complexes with water-soluble Schiff base ligands: Synthesis and catalytic activity in transfer hydrogenation of carbonyl compounds

被引：15

作者：

Talouki, Somayeh Azizi ^{[1
]}

Grivani, Gholamhossein ^{[1
]}

Crochet, Pascale ^{[2
]}

Cadierno, Victorio ^{[2
]}

机构：

[1] Damghan Univ, Sch Chem, Damghan 36715364, Iran

[2] Univ Oviedo, Inst Univ Quim Organometal Enrique Moles, Dept Quim Organ & Inorgan,Lab Compuestos Organome, Ctr Innovac Quim Avanzada ORFEO CINQA, E-33006 Oviedo, Spain

来源：

INORGANICA CHIMICA ACTA | 2017年 / 456卷

关键词：

Schiff-base ligands; Ionic ligands; Ruthenium; Transfer hydrogenation; Ketones; Aqueous catalysis; ASYMMETRIC TRANSFER HYDROGENATION; METAL-COMPLEXES; HYDRATION REACTIONS; ANTICANCER ACTIVITY; CRYSTAL-STRUCTURE; IMIDAZOLIUM SALT; ARENE COMPLEXES; BOND FORMATION; IONIC LIQUIDS; DNA-BINDING;

D O I：

10.1016/j.ica.2016.10.041

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New ionic Schiff-base ligands have been synthesized by condensation of (3-formyl-4-hydroxybenzyl) triphenylphosphonium and 3-(3-formyl-4-hydroxybenzyl)-1-methyl-1H-imidazol-3-ium chloride and hexafluorophosphate salts with N,N-dimethylethylenediamine. Treatment of the dimeric derivative [{RuCl(mu-Cl)(eta(6)-p-cymene)}2] with two equivalents of these ligands allowed the preparation of novel mononuclear water-soluble Ru(II) complexes, which proved to be catalytically active in the transfer hydrogenation of ketones and aldehydes under aqueous conditions. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：142 / 148

页数：7

共 82 条

[1]

Abd Karim N. H., 2014, RSC ADV, V4, P3355, DOI DOI 10.1039/C1CC11737H

[2] Arene Ruthenium Complexes as Versatile Catalysts in Water in both Transfer Hydrogenation of Ketones and Oxidation of Alcohols. Selective Deuterium Labeling of rac-1-Phenylethanol [J].