Study of the A1Σ+ and b3Π0 states in LiCs by a polarization labelling spectroscopy technique

被引：9

作者：

Grochola, A. ^{[1
]}

Szczepkowski, J. ^{[2
]}

Jastrzebski, W. ^{[2
]}

Kowalczyk, P. ^{[1
]}

机构：

[1] Univ Warsaw, Dept Phys, Inst Expt Phys, PL-00681 Warsaw, Poland

[2] Polish Acad Sci, Inst Phys, PL-02668 Warsaw, Poland

来源：

JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER | 2014年 / 145卷

关键词：

Diatomic molecules; Electronic states; Potential energy curves; Laser spectroscopy; Perturbations in molecular spectra; ELECTRONIC-STRUCTURE;

D O I：

10.1016/j.jqsrt.2014.04.029

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

A polarization labelling spectroscopy technique was used to investigate the A(1)Sigma(+) <- X-1 Sigma(+) band system of the (LiCs)-Li-7 molecule in a heat-pipe oven. All 27 observed vibrational levels of the A state were found to be subject to strong perturbations assigned to interaction with the b(3)Pi (0) state. The deperturbation analysis provided molecular constants of the A and b states and a value of the electronic part of the spin-orbit interaction matrix element b(3)Pi(0)vertical bar H-so vertical bar A(1)Sigma(+). (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：147 / 152

页数：6

共 27 条

[1] Direct coupled-channels deperturbation analysis of the A1Σ+ ∼ b3Π complex in LiCs with experimental accuracy
Kowalczyk, P.
Jastrzebski, W.
Szczepkowski, J.
Pazyuk, E. A.
Stolyarov, A. V.
JOURNAL OF CHEMICAL PHYSICS, 2015, 142 (23)
[2] Analogue of oscillation theorem for nonadiabatic diatomic states: application to the A1Σ+ and b3Π states of KCs
Pupyshev, V. I.
Pazyuk, E. A.
Stolyarov, A. V.
Tamanis, M.
Ferber, R.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2010, 12 (18) : 4809 - 4812
[3] Experimental study of the 61Π and 71Π states of NaK by polarization labeling spectroscopy technique
Grochola, A
Jastrzebski, W
Kortyka, P
Kowalczyk, P
JOURNAL OF MOLECULAR SPECTROSCOPY, 2003, 221 (02) : 279 - 284
[4] Characterisation of the b3Σ+, v=0 state and its interaction with the A1Π state in aluminium monofluoride
Doppelbauer, M.
Walter, N.
Hofsass, S.
Marx, S.
Schewe, H. C.
Kray, S.
Perez-Rios, J.
Sartakov, B. G.
Truppe, S.
Meijer, G.
MOLECULAR PHYSICS, 2021, 119 (1-2)
[5] Observation of D(2)1 Π ∼ (2)3 Π ∼ (2)3 Σ+ states in KCs by polarisation labelling spectroscopy technique. Modelling of the D(2)1 Π ∼ (2)3 Π1 system
Szczepkowski, Jacek
Grochola, Anna
Kowalczyk, Pawel
Jastrzebski, Wlodzimierz
JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER, 2020, 248
[6] Transition properties of X1 Σ+, A1Σ-, B1 Δ, C1 Π, a3 Σ+, b3 Δ, c3 Π, and d3 Σ- states of PO+
Zhang, Meng
Shi, Deheng
JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER, 2021, 264
[7] The C1Πu state of Na2 revisited:: A comprehensive study by polarization labeling spectroscopy technique
Grochola, A
Jastrzebski, W
Kowalczyk, P
JOURNAL OF MOLECULAR SPECTROSCOPY, 2005, 232 (02) : 291 - 295
[8] The branching ratio of intercombination A1Σ+ ∼ b3Π → a3Σ+ /X1Σ+ transitions in the RbCs molecule: Measurements and calculations
Krumins, V
Kruzins, A.
Tamanis, M.
Ferber, R.
Pashov, A.
Oleynichenko, A., V
Zaitsevskii, A.
Pazyuk, E. A.
Stolyarov, A., V
JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER, 2020, 256 (256)
[9] Spectroscopic and molecular properties of X1Σ+, a3Σ+, b3Π, d3Δ, C1Σ-, e3Σ-, D1Δ and A1Π electronic states of SiS molecule
Shi, Deheng
Xing, Wei
Zhang, Xiaoniu
Sun, Jinfeng
Zhu, Zunlue
Liu, Yufang
COMPUTATIONAL AND THEORETICAL CHEMISTRY, 2011, 969 (1-3) : 17 - 26
[10] Fourier-transform spectroscopy and global deperturbation treatment of the <mml:msup>A1</mml:msup>Σu+ and b3Πu states of K2 in the entire bound energy range
Klincare, I.
Lapins, A.
Tamanis, M.
Ferber, R.
Zaitsevskii, A.
Pazyuk, E. A.
Stolyarov, A. V.
JOURNAL OF CHEMICAL PHYSICS, 2024, 160 (06)

← 1 2 3 →