Synthesis, characterization and molecular structure of bis(2,2′-bipyridine-N,N′)-bis(monochloroacetato-O) manganese(II) dihydrate

被引：8

作者：

Czylkowska, A ^{[1
]}

Kruszynski, R ^{[1
]}

Czakis-Sulikowska, D ^{[1
]}

Bartczak, TJ ^{[1
]}

机构：

[1] Tech Univ Lodz, Inst Gen & Ecol Chem, PL-90924 Lodz, Poland

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2004年 / 57卷 / 03期

关键词：

manganese(II); 2,2 '-bipyridine; monochloroacetate; crystal structure;

D O I：

10.1080/00958970410001671246

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Mn(2-bPY)(2)(mcac-O)(2)].2H(2)O (2-bpy = 2,2'-bipyridine, mcac = ClCH2COO-) has been synthesized and characterized by elemental and thermal analysis, IR, magnetic and conductivity studies. It crystallizes in space group P2(1)/n. The manganese atom adopts a significantly distorted square bipyramidal coordination. Mn-O bonds are distinctly stronger than Mn-N bonds. Molecules of the title compound are linked by strong hydrogen bonds O-H...O(acetate) to form an infinite hydrogen-bonded chain. The hydrogen-bonded chains are assembled via weak C-H... 0 hydrogen bonds leading to a three-dimensional net structure.

引用

页码：239 / 247

页数：9

共 37 条

[1] STRUCTURAL INFORMATION ON MANGANESE(II) CHLORIDE, THIOCYANATE, ACETATE AND SULFATE COMPLEXES WITH 2,2'-BIPYRIDYL, 4,4'-BIPYRIDYL AND THEIR DIOXIDES FROM THEIR MAGNETIC-MOMENTS, ELECTRONIC AND INFRARED-SPECTRA [J].

AHUJA, IS ;

SINGH, R ;

YADAVA, CL .

JOURNAL OF MOLECULAR STRUCTURE, 1981, 74 (01) :143-151

[2] HYDROFORMYLATION OF OLEFINS CATALYZED BY SUPPORTED RU3(CO)12 WITH 2,2'-BIPYRIDINE OR WITH OTHER HETEROCYCLIC NITROGEN BASE [J].

ALVILA, L ;

PAKKANEN, TA ;

KRAUSE, O .

JOURNAL OF MOLECULAR CATALYSIS, 1993, 84 (02) :145-156

[3] SYNTHESES AND STRUCTURES OF 3 MONONUCLEAR COORDINATION-COMPOUNDS CONTAINING 6-COORDINATED AND 7-COORDINATED MANGANESE(II) IONS [J].

ANDRUH, M ;

HUBNER, K ;

NOLTEMEYER, M ;

ROESKY, HW .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1993, 48 (05) :591-597

[4] Synthesis, characterization and crystal structure of diaquadi(acetato-O)-bis(2,4′-bipyridyl) manganese(II) [J].

Bartczak, TJ ;

Czakis-Sulikowska, D ;

Kaluzna, J .

JOURNAL OF COORDINATION CHEMISTRY, 1998, 46 (02) :193-202

[5] Influence of chemical and spatial constraints on the structures of inorganic compounds [J].

Brown, ID .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1997, 53 :381-393

[6] Spectral and thermal studies of Mn(II), Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) complexes with 3-methylglutaric acid [J].

Brzyska, W ;

Ozga, W .

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2000, 61 (01) :135-142

[7] Coordination polymers of copper(II) based on mixed N- and O-donor ligands:: the crystal structures of [CuL2(4,4′-bipy)]n (L = lactate or 2-methyllactate) [J].

Carballo, R ;

Castiñeiras, A ;

Covelo, B ;

Vázquez-López, EM .

POLYHEDRON, 2001, 20 (9-10) :899-904

[8] STRUCTURE OF CATENA-POLY[((2,2'-BIPYRIDYL)(DIPERCHLORATO)COPPER(II))-MU-4,4'-BIPYRIDYL] [J].

CHEN, CG ;

XU, DJ ;

XU, YZ ;

CHENG, CR ;

LING, RG .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1992, 48 :1231-1233

[9] Thermal and other properties of complexes of Mn(II), Co(II) and Ni(II) with 2,2′-bipyridine and trichloroacetates [J].

Czakis-Sulikowska, D ;

Czylkowska, A .

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2003, 74 (01) :349-360

[10]

Czakis-Sulikowska D, 2003, POL J CHEM, V77, P1363

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