Coordination polymers based on pyrazole-4-carboxaldehyde-containing Cu3N6 metallacycles as building units

被引：7
|
作者：
Kreiger, David I. [1 ]
Mathivathanan, Logesh [1 ]
Raptis, Raphael G. [1 ]
机构：
[1] Florida Int Univ, Dept Chem & Biochem, 11200 SW 8th St, Miami, FL 33199 USA
来源：
CRYSTENGCOMM | 2019年 / 21卷 / 19期
基金：
美国国家科学基金会;
关键词：
OXYGEN-CONTAINING LIGANDS; METAL-ORGANIC FRAMEWORK; STRUCTURAL-CHARACTERIZATION; MAGNETIC-PROPERTIES; MIXED-VALENT; PYRAZOLATE; COMPLEXES; CRYSTAL; COPPER(I); ALDEHYDE;
D O I：
10.1039/c9ce00421a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Five crystal structures containing trinuclear Cu(II)-4-formyl pyrazolato units are reported: a 0-D Cu-3 complex ((Ph4P)(2)[1]) was prepared in the presence of terminal chloride ligands, a 3D polymer with dia topology and 3-fold interpenetrated structure ([2](CF3SO3)(2)) involved 1,2-bipyridylethylene (bpe) linkers, while a second 1-D polymer ([3](CF3SO3)(2)) formed by linking SBUs via formyl group coordination. Two 3D polymers ([4](CF3SO3)(2) and [5](ClO4)(2)) with novel topologies consist of 14-nodal 3(8),4(2),5(4)-c and 3-nodal 3,3,4-c nets, respectively.
引用
收藏
页码：3047 / 3055
页数：9
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