A novel trinuclear Cd(II) cluster-based metal-organic framework: synthesis, structure and luminescence properties

被引：8
作者：
Wang, Jia [1 ]
Yao, Shuo [1 ]
Li, Guanghua [1 ]
Huo, Qisheng [1 ]
Zhang, Lirong [1 ]
Liu, Yunling [1 ]
机构：
[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
来源：
RSC ADVANCES | 2015年 / 5卷 / 124期
关键词：
COORDINATION POLYMERS; HYDROGEN STORAGE; LIGAND; MOF; CONSTRUCTION; CADMIUM(II); PERFORMANCE; ADSORPTION; DIVERSITY; TOPOLOGY;
D O I：
10.1039/c5ra22184f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel three-dimensional metal-organic framework (MOF), [H3O][Cd3Cl(PZC)(3)(H2O)(3)] (1), has been synthesized based on a trinuclear Cd(II) cluster and H(2)PZC ligand (H(2)PZC = 1H-pyrazole-4-carboxylic acid). Compound 1 crystallizes in a trigonal crystal system with the space group R3m. Trinuclear Cd(II)-clusters as secondary building units (SBU) are further connected by the H(2)PZC ligand to form a two-fold interpenetrated 3D framework. Compound 1 exhibits excellent water-stability and good luminescence properties for various organic solvents and different metal ions. The systematic investigation for luminescence indicates that compound 1 possesses unique performance for the detection of acetone, Fe2+ and Na+ based on a fluorescence quenching and enhancing mechanism, thus it can be regarded as a potential luminescence probe for the detection of acetone, Fe2+ and Na+.
引用
收藏
页码：102525 / 102529
页数：5
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