Classification of terpene oils using the fish diagrams and the Equivalent Alkane Carbon (EACN) scale

被引:45
作者
Bouton, Francois [1 ]
Durand, Morgan [1 ]
Nardello-Rataj, Veronique [1 ]
Serry, Marie [1 ]
Aubry, Jean-Marie [1 ]
机构
[1] ENSCL, CNRS, Equipe Oxydat & Formulat, LCOM,UMR 8009, F-59652 Villeneuve Dascq, France
关键词
Fragrance; Fish diagram; Hydrophilic-Lipophilic Deviation (HLD); Terpenes; Equivalent Alkane Carbon Number (EACN); PHASE-BEHAVIOR; FRAGRANCE COMPOUNDS; WATER SYSTEMS; MICROEMULSIONS; SOLUBILIZATION; CONDUCTIVITY; SURFACTANTS; LOCATION; PERFUME; ETHERS;
D O I
10.1016/j.colsurfa.2008.05.027
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The phase behaviour of ternary systems based on tetraethylene glycol monoalkyl ether (CiE4) as surfactants and a series of mono- and sesqui-terpenes as fragrance oils was investigated by resorting to the HLD (Hydrophilic-Lipophilic Deviation) concept. Each ternary system was studied by localizing the critical point (T*, C*) in the fish diagram and the terpenes were characterized by their Equivalent Alkane Carbon Number (EACN). EACN values have been rationalized by considering structural changes of the terpenes, Such as number of carbons, branching, cyclisation, unsaturation and aromatisation. The C8E4/caryophyllene/water fish diagram has been established and compared with the alkane of closest ACN, i.e. hexane. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:142 / 147
页数:6
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