Dielectric properties of CdS nanoparticles synthesized by soft chemical route

被引:30
|
作者
Tripathi, R. [1 ]
Kumar, A. [1 ]
Sinha, T. P. [2 ]
机构
[1] Govt Postgrad Coll, Dept Phys, Rishikesh 249 201, India
[2] Bose Inst, Dept Phys, Kolkata 700 009, India
来源
PRAMANA-JOURNAL OF PHYSICS | 2009年 / 72卷 / 06期
关键词
Cadmium sulphide; chemical synthesis; impedance spectroscopy; dielectric properties; RELAXATION; CLUSTERS;
D O I
10.1007/s12043-009-0089-5
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
CdS nanoparticles have been synthesized by a chemical reaction route using thiophenol as a capping agent. The frequency-dependent dielectric dispersion of cadmium sulphide (CdS) is investigated in the temperature range of 303-413 K and in a frequency range of 50 Hz-1 MHz by impedance spectroscopy. An analysis of the complex permittivity (epsilon' and epsilon '') and loss tangent (tan delta) with frequency is performed by assuming a distribution of relaxation times. The scaling behaviour of dielectric loss spectra suggests that the relaxation describes the same mechanism at various temperatures. The frequency-dependent electrical data are analysed in the framework of conductivity and modulus formalisms. The frequency-dependent conductivity spectra obey the power law.
引用
收藏
页码:969 / 978
页数:10
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