Synthesis, crystal structure, and antimicrobial activity of a novel chlorido-bridged dinuclear manganese(III) complex derived from N,N′-bis(5-methylsalicylidene)diethylenetriamine

被引：3

作者：

Hu, Xiao-Ming ^{[1
]}

Zhao, Gan-Qing ^{[1
]}

Xue, Ling-Wei ^{[1
]}

Yang, Wei-Chun ^{[1
]}

机构：

[1] Pingdingshan Univ, Coll Chem & Chem Engn, Pingdingshan 467000, Henan, Peoples R China

来源：

INORGANIC AND NANO-METAL CHEMISTRY | 2017年 / 47卷 / 01期

关键词：

Schiff base; manganese complex; crystal structure; dinuclear complex; antibacterial activity; SCHIFF-BASE; COPPER(II) COMPLEXES; ANTIBACTERIAL; NICKEL(II); ABSORPTION;

D O I：

10.1080/15533174.2016.1149726

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel chlorido-bridged dinuclear manganese(III) complex, [Mn2L2(mu-Cl)Cl-2)]center dot Cl center dot 0.5CH(3)OH, where L is the zwitterionic form of N, N'-bis(5-methylsalicylidene) diethylenetriamine, has been prepared and characterized by elemental analyses, IR, and single-crystal X-ray crystallographic determination. The crystal of the complex is monoclinic: space group C2/c, a = 20.0300(9), b = 22.8494(8), c = 22.127(1) angstrom, beta = 112.882(3)degrees, V = 9330.0 (7) angstrom(3), Z = 8. The asymmetric unit of the compound contains two dinuclear manganese complex cations, two chloride anions, and one methanol solvate. The Schiff base ligand coordinates to two Mn atoms through the phenolate O and imine N atoms, with the amine N atom protonated. The effect of the complex on the antimicrobial activity against Staphylococcus aureus, Escherichia coli, and Candida albicans was studied.

引用

页码：91 / 94

页数：4

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