Studies and characterization of mixed ligand complexes of aluminium with (N-O) and (N--S) donor ligands

被引:0
|
作者
Gothwal, Y. K. [1 ]
Joshi, Jyoti
Joshi, Bidya S.
机构
[1] Univ Rajasthan, Dept Chem, Jaipur 302004, Rajasthan, India
[2] Malviya Natl Inst Technol, Dept Chem, Jaipur 302017, Rajasthan, India
关键词
mixed aluminium(III) complexes; N-phenylsalicylaldimine; 3-(phenylamino)-1-phenyl-2-butene-1-one; 3-aryl-2-mercapto-4(3H)quinazolones; hexacoordinate;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis of some aluminium(III) mixed ligand complexes having NO donor Schiffs bases, N-phenylsalicylaldimine (SLIMH) and 3-(phenylamino)-1-phenyl-2-butene-1-one (BZAMH), with 3-aryl-2-mercapto-4(3H)quinazolones (MAQH) has been reported. The mixed ligand complexes were obtained by the reaction of (Schiffs base)(2) aluminium isopropoxy precursors with the mercapto ligands. The complexes were characterized by elemental analysis and spectral studies. The studies reveal the formation of hexacoordinate complexes with NS bonding of the mercapto ligands.
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页码:2809 / 2812
页数:4
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