Palladium-catalyzed thiolation of alkanes and ethers with arylsulfonyl hydrazides

被引：115

作者：

Guo, Sheng-rong ^{[1
,2
]}

He, Wei-ming ^{[1
]}

Xiang, Jian-nan ^{[1
]}

Yuan, Yan-qin ^{[2
]}

机构：

[1] Hunan Univ, Coll Chem & Chem Engn, Changsha 410082, Hunan, Peoples R China

[2] Lishui Univ, Dept Chem, Lishui 323000, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 62期

基金：

湖南省自然科学基金;

关键词：

C-H BOND; SULFONYL HYDRAZIDES; REGIOSELECTIVE SULFENYLATION; DISULFIDES; CLEAVAGE; ALPHA; SULFONYLHYDRAZIDES; CHLORIDES; SULFIDES; INDOLES;

D O I：

10.1039/c4cc02876g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new method for the preparation of alkyl aryl sulfides through direct oxidative thiolation of alkanes or ethers with arylsulfonyl hydrazides using di-tert-butyl peroxide (DTBP) as an oxidant catalyzed by Pd(OAc)(2) has been reported. The C-H bonds in various alkanes or ethers were successfully converted into C-S bonds to yield the corresponding sulfides in moderate to good yields.

引用

页码：8578 / 8581

页数：4

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