A Chemiluminescent Metal-Organic Framework

被引：33
|
作者：
Ruehle, Bastian [1 ,2 ,3 ]
Virmani, Erika [1 ,2 ]
Engelke, Hanna [1 ,2 ]
Hinterholzinger, Florian M. [1 ,2 ]
von Zons, Tobias [4 ,5 ]
Brosent, Birte [4 ,5 ]
Bein, Thomas [1 ,2 ]
Godt, Adelheid [4 ,5 ]
Wuttke, Stefan [1 ,2 ,6 ]
机构：
[1] Univ Munich LMU, Dept Chem, Butenandtstr 11 E, D-81377 Munich, Germany
[2] Univ Munich LMU, Ctr NanoSci CeNS, Butenandtstr 11 E, D-81377 Munich, Germany
[3] BAM Fed Inst Mat Res & Testing, Div Biophoton 1 2, Richard Willstaetter Str 11, D-12489 Berlin, Germany
[4] Bielefeld Univ, Fac Chem, Univ Str 25, D-33615 Bielefeld, Germany
[5] Bielefeld Univ, Ctr Mol Mat CM2, Univ Str 25, D-33615 Bielefeld, Germany
[6] Univ Lincoln, Sch Chem, Joseph Banks Labs, Lincoln LN6 7TS, England
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2019年 / 25卷 / 25期
关键词：
chemiluminescence; metal-organic framework; MOF; thin film; UiO; CATALYTIC CHEMILUMINESCENCE; PHOTOLUMINESCENCE; CHEMISTRY; SYSTEM;
D O I：
10.1002/chem.201806041
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis and characterization of a chemiluminescent metal-organic framework with high porosity is reported. It consists of Zr6O6(OH)(4) nodes connected by 4,4'(anthracene-9,10-diyl) dibenzoate as the linker and luminophore. It shows the topology known for UiO-66 and is therefore denoted PAP-UiO. The MOF was not only obtained as bulk material but also as a thin film. Exposure of PAP-UiO as bulk or film to a mixture of bis-(2,4,6-trichlorophenyl) oxa-late, hydrogen peroxide, and sodium salicylate in a mixture of dimethyl and dibutyl phthalate evoked strong and long lasting chemiluminescence of the PAP-UiO crystals. Time dependent fluorescence spectroscopy on bulk PAP-UiO and, for comparison, on dimethyl 4,4'-(anthracene-9,10-diyl) dibenzoate provided evidence that the chemiluminescence originates from luminophores being part of the PAP-UiO, including the luminophores inside the crystals.
引用
收藏
页码：6349 / 6354
页数：6
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