Diorganotin(IV) derivatives of tridentate dithiocarbazones - Structure determination in the solid and liquid state

被引：12
作者：
Knoll, S
Tschwatschal, F
Ristau, T
Gelbrich, T
Borsdorf, R
Zahn, G
机构：
[1] UNIV LEIPZIG,INST ANALYT CHEM,FAK CHEM & MINERAL,D-04103 LEIPZIG,GERMANY
[2] UNIV LEIPZIG,INST ANORGAN CHEM,D-04103 LEIPZIG,GERMANY
[3] TECH UNIV DRESDEN,INST KRISTALLOG & FESTKORPERPHYS,D-8027 DRESDEN,GERMANY
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1997年 / 623卷 / 01期
关键词：
diorganotin complexes; dithiocarbazone complexes; chelate complexes; crystal structure; ir-; mass-; multinuclear nmr spectra; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURE; ACID-DERIVATIVES; COMPLEXES; THIOSEMICARBAZONE;
D O I：
10.1002/zaac.19976230123
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The tridentate ligands with the S-Methyldithiocarbazate Schiff Base of 2-Salicylaldehyde (H(2)Sal) and 2-Pyridinaldehyde (HPyr) react in different way with diorganotin(IV) oxides, in the first case to the five-coordinate complex R(2)Sn-Sal with trigonal bipyramidal structure and in the second case to the binuclear complex [(R(2)Sn-Pyr)(2)CO3] with a bridging carbonat anion. The structures were elucidated by X-ray diffraction and by multinuclear NMR in solution. IR- and Mass-spectrometric measurements complete the results.
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收藏
页码：141 / 146
页数：6
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