Several tripodal diimine ligands, tris(2-(2-thiazolyl)methyliminoethyl)amine, 2-Tatren, tris(2-(4-(5-methyl)imidazolyl)methyliminoethyl)amine, 5-Me-4-Imtren, tris(2-(4-imidazolyl)methyliminoethyl)amine, 4-Imtren, tris(2-(2-imidazolyl)methyliminoethyl)amine, 2-Imtren, and their Mg2+ complexes were prepared and characterized. X-ray diffraction studies show that the Mg2+ ions are six-coordinate, with three acyclic imine N atoms and three imidazolyl or thiazolyl N atoms coordinated with the general formula [Mg(L)](ClO4)(2) (L = 4-Imtren (1), 2-Imtren (2), 2-Tatren (3), and 5-Me-4-Imtren (4)). These complexes are chiral with both A and A isomers present in the unit cell. H-1 NMR titrations reveal that complexes also form in solution and that the chirality is maintained. Variable temperature H-1 NMR reveals that the Delta and Lambda isomers interconvert in the intermediate to slow time scale. The interconversion rate slows with increasing pK(a) of the ligand heterocycle, suggesting that interconversion proceeds through a partially dissociated state. These complexes undergo traus-metallation by Zn2+, indicating that their ligands can be released in a kinetically facile manner to form more stable metal ion complexes. (C) 2004 Elsevier Inc. All rights reserved.