Novel fabrication of an efficient solid base: carbon-doped MgO-ZnO composite and its CO2 capture at 473 K

被引：34

作者：

Li, Yan Yan ^{[1
]}

Wan, Mi Mi ^{[1
]}

Sun, Xiao Dan ^{[1
]}

Zhou, Jun ^{[2
]}

Wang, Ying ^{[2
,3
]}

Zhu, Jian Hua ^{[1
]}

机构：

[1] Nanjing Univ, Key Lab Mesoscop Chem MOE, Coll Chem & Chem Engn, Nanjing 210093, Jiangsu, Peoples R China

[2] Nanjing Univ, Coll Chem & Chem Engn, Nanjing 210093, Jiangsu, Peoples R China

[3] Nanjing Univ, Ecomat & Renewable Energy Res Ctr ERERC, Nanjing 210093, Jiangsu, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2015年 / 3卷 / 36期

关键词：

OPTICAL-PROPERTIES; ADSORPTION; BASICITY; PERFORMANCE; DIOXIDE; SURFACE; GENERATION; ALKYLATION; CATALYSTS; MAGNESIA;

D O I：

10.1039/c5ta04309c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new strategy for fabricating an optimal porous strong base was reported for the first time. Magnesium and zinc acetates were mixed by microwave irradiation followed by carbonization at 823 K. Zn incorporation enabled the magnesia nanoparticles to have more surface defects, and about 80% of the basic sites were strong ones with the ability to capture CO2 at 473 K, which is the highest proportion to date. These porous binary metal oxides had large surface areas between 130-296 m(2) g(-1).

引用

页码：18535 / 18545

页数：11

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