Electrically and thermally conductive nylon 6,6

被引:91
作者
King, JA [1 ]
Tucker, KW [1 ]
Vogt, BD [1 ]
Weber, EH [1 ]
Quan, CL [1 ]
机构
[1] Michigan Technol Univ, Dept Chem Engn, Houghton, MI 49931 USA
关键词
D O I
10.1002/pc.10387
中图分类号
TB33 [复合材料];
学科分类号
摘要
Increasing the thermal and electrical conductivity of typically insulating polymers, such as nylon 6,6, opens new markets, A thermally conductive resin can be used for heat sink applications. An electrically conductive resin can be used in static dissipative and Electromagnetic Interference/Radio Frequency Interference shielding applications. This research focused on adding various carbon based conductive fillers and a chopped glass fiber to nylon 6,6. These materials were extruded and injection molded into test specimens. Tensile tests as well as in-plane electrical resistivity, in-plane thermal conductivity, and through-plane thermal conductivity tests were conducted. One successful formulation consisted of 10% 3.2 mm chopped E-glass fiber/15% Thermocarb (high quality synthetic powdered graphite)/5% carbon black/70% nylon 6,6 (all % in wt%). For this formulation, the in-plane electrical resistivity was reduced from 10(15) ohm-cm (neat nylon 6,6) to 15 ohm-cm. The through-plane thermal conductivity increased from 0.25 W/mK (neat nylon 6,6) to 0.7 W/mK. The tensile elongation at failure was 1.4%.
引用
收藏
页码:643 / 654
页数:12
相关论文
共 18 条
[1]   THERMAL-CONDUCTIVITIES OF COMPOSITES IN SEVERAL TYPES OF DISPERSION-SYSTEMS [J].
AGARI, Y ;
UEDA, A ;
NAGAI, S .
JOURNAL OF APPLIED POLYMER SCIENCE, 1991, 42 (06) :1665-1669
[2]   THERMAL-CONDUCTIVITY OF POLYMER FILLED WITH CARBON MATERIALS - EFFECT OF CONDUCTIVE PARTICLE CHAINS ON THERMAL-CONDUCTIVITY [J].
AGARI, Y ;
UNO, T .
JOURNAL OF APPLIED POLYMER SCIENCE, 1985, 30 (05) :2225-2235
[3]  
[Anonymous], 1992, MODERN PLASTICS US
[4]  
*ASTM, 1998, 63897 ASTM D
[5]  
*ASTM, 1996, 43377 ASTM F
[6]   CONDUCTIVE POLYMERIC COMPOSITIONS [J].
BIGG, DM .
POLYMER ENGINEERING AND SCIENCE, 1977, 17 (12) :842-847
[7]   THERMALLY CONDUCTIVE POLYMER COMPOSITIONS [J].
BIGG, DM .
POLYMER COMPOSITES, 1986, 7 (03) :125-140
[8]   THE EFFECT OF FIBER CONCENTRATION ON THE THERMAL-CONDUCTIVITY OF A POLYCARBONATE PITCH-BASED CARBON-FIBER COMPOSITE [J].
DEMAIN, A ;
ISSI, JP .
JOURNAL OF COMPOSITE MATERIALS, 1993, 27 (07) :668-683
[9]  
DEMAIN A, 1994, THESIS U CATHOLIQUE
[10]  
GERTEISEN S, 1985, P SPE 43 ANN TECHN C