A study on the equilibrium reaction of benzaldehyde and sodium bisulphite by in situ Fourier transform IR spectroscopy

被引:4
作者
Sallay, Peter [1 ]
Szilagyi, Nikolett [1 ]
Csontos, Istvan [1 ]
Keglevich, Gyoergy [1 ]
机构
[1] BME, Dept Organ Chem & Technol, H-1111 Budapest, Hungary
关键词
in situ Fourier transform IR spectroscopy; monitoring; equilibrium; benzaldehyde - sodium bisulphite adduct; INFRARED-SPECTROSCOPY; OXIMATION; KINETICS; SYSTEM;
D O I
10.3311/pp.ch.2009-1.02
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The addition of sodium bisulphite to benzaldehyde was monitored at different conditions by in situ Fourier transform IR spectroscopy and the equilibrium constant was determined.
引用
收藏
页码:9 / 12
页数:4
相关论文
共 10 条
[1]  
ENDE DJ, 2000, CURR OPIN DRUG DISC, V3, P699
[2]   The chemical reaction equilibrium constant and standard molar enthalpy change for the reaction {2HSO3-(aq)⇆S2O52-(aq)+H2O(1)1}:: a spectroscopic and calorimetric investigation [J].
Ermatchkov, V ;
Kamps, APS ;
Maurer, G .
JOURNAL OF CHEMICAL THERMODYNAMICS, 2005, 37 (02) :187-199
[3]  
KEGLEVICH G, 2006, MAGYAR KEMIAI FOLYOI, V112, P114
[4]   A study of the pH dependence of the two-step oximation of acetone by in situ Fourier transform infrared spectroscopy [J].
Keglevich, Gyoergy ;
Csontos, Istvan ;
Szilagyi, Nikolett ;
Greiner, Istvan .
CHEMICAL ENGINEERING & TECHNOLOGY, 2008, 31 (03) :421-425
[5]   Monitoring the pH-Dependent Oximation of Methyl Ethyl Ketone and Benzaldehyde by in situ Fourier Transform IR Spectroscopy in a Heterogeneous Liquid-Liquid Two-Phase System [J].
Keglevich, Gyorgy ;
Csontos, Istvan ;
Nikolett Szilagyi .
SPECTROSCOPY LETTERS, 2009, 42 (02) :67-72
[6]   KINETICS, THERMODYNAMICS, AND MECHANISM OF THE FORMATION OF BENZALDEHYDE-S(IV) ADDUCTS [J].
OLSON, TM ;
BOYCE, SD ;
HOFFMANN, MR .
JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (11) :2482-2488
[7]   In situ Fourier transform infrared spectroscopy as an efficient tool for determination of reaction kinetics [J].
Pintar, A ;
Batista, J ;
Levec, J .
ANALYST, 2002, 127 (11) :1535-1540
[8]  
REIN AJ, 1992, SPIE OPTICALLY BASED, V1681
[9]  
SHERIDAN RE, 1991, R&D MAG, V33, P100
[10]   Catalytic asymmetric cyano-phosphorylation of aldehydes using a YLi3tris(binaphthoxide) complex (YLB) [J].
Yamagiwa, N ;
Abiko, Y ;
Sugita, M ;
Tian, J ;
Matsunaga, S ;
Shibasaki, M .
TETRAHEDRON-ASYMMETRY, 2006, 17 (04) :566-573