Chiral monolayer of self-assembled Delta-[Os(bpy)(2)L(Cl)](+) [bpy equals 2,2'-bipyridyl L=1,2-bis(4-pyridyl)ethane] on a platinum electrode

被引：16

作者：

Inose, Y

Moniwa, S

Aramata, A

Yamagishi, A

KyawNaing

机构：

[1] HOKKAIDO UNIV,CTR CATALYSIS RES,SAPPORO,HOKKAIDO 060,JAPAN

[2] HOKKAIDO UNIV,GRAD SCH SCI,SAPPORO,HOKKAIDO 060,JAPAN

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 01期

关键词：

D O I：

10.1039/a606791c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A chiral osmium Complex, Delta-(2,2'-bipyridyl) [1,2-bis(4-pyridyl)ethane] chloroosmium Delta-[Os(bpy)(2)L(Cl)](+), is successfully self-assembled at a monolayer molecular level on a clean Pt electrode in non-aqueous solutions; the self-assembled Delta-[Os(bpy)(2)LCl](+) ions show a phenomenally repulsive interaction with each other on Pt in chiral-field formation and also in the (OsOsIII)-Os-II redox reaction, while racemic complexes interact less repulsively with each other.

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页码：111 / 112

页数：2

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