Cobalt-catalyzed intramolecular Heck-type reaction of 6-halo-1-hexene derivatives

被引：86

作者：

Fujioka, T ^{[1
]}

Nakamura, T ^{[1
]}

Yorimitsu, H ^{[1
]}

Oshima, K ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Kyoto 6068501, Japan

来源：

ORGANIC LETTERS | 2002年 / 4卷 / 13期

关键词：

D O I：

10.1021/ol0261128

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of 6-iodo-1-hexene derivatives with trimethylsilylmethyl Grignard reagent in the presence of CoCl2(dppb) in refluxing THF affords Heck-type products, methylenecyclopentanes, in good yields.

引用

页码：2257 / 2259

页数：3

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