Enantioselective Synthesis of Axially Chiral Biaryls by Organocatalysis - Approaches Based on Stereoselective Construction of Alicyclic Precursors-

被引：0

作者：

Yamaguchi, Satoru

机构：

来源：

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 2019年 / 77卷 / 06期

关键词：

ATROPISOMERIC BIARYLS; ARYLATION; RESOLUTION;

D O I：

10.5059/yukigoseikyokaishi.77.605

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A number of organocatalytic methods for the synthesis of axially chiral biaryl compounds have been reported to date, and most of them are predicated on desymmetrization of achiral biaryl precursors or dynamic kinetic resolution of stereo labile biaryl precursors. This mini-review highlights the alternative approaches utilizing the aromatization of alicyclic intermediates derived through the stereoselective organocatalytic reactions.

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页码：605 / 607

页数：3

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