Intense red emission of mixed-alkali rare-earth free germanate glass-ceramics with Mn ions

被引:6
作者
Babkina, Anastasiia [1 ]
Valiev, Damir [2 ]
Kulpina, Ekaterina [1 ]
Pavliuk, Aleksandra [1 ]
Zyryanova, Ksenia [1 ]
Monogarova, Alina [1 ]
Ignatiev, Alexander [1 ]
Kuzmenko, Natalia [1 ]
Zhizhin, Evgeny [3 ]
Koroleva, Aleksandra [3 ]
机构
[1] ITMO Univ, 4 Birzhevaya Line, St Petersburg 199034, Russia
[2] Natl Res Minsk Polytech Univ, 30 Lenin Ave, Minsk 634050, BELARUS
[3] St Petersburg Univ, 7-9 Univ Skaya Nab, St Petersburg 199034, Russia
基金
俄罗斯科学基金会;
关键词
PHASE-EQUILIBRIA; OXIDE SYSTEMS; PHOTOLUMINESCENCE PROPERTIES; CRYSTALLIZATION RESEARCH; OPTICAL SPECTROSCOPY; PHOSPHOR; LUMINESCENCE; LINAGE4O9; DISORDER; DESIGN;
D O I
10.1364/OME.458233
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A series of germanate glasses with manganese and alkaline ions (Li, Na, K, Rb, Cs) are successfully synthesized. Only 9 out of 21 studied compositions crystallize into glass-ceramics with LiNaGe4O9 and Li2Ge7O15 nanocrystals. The glass-ceramics possess intense emission near 660-670 nm with 37% QY and two-exponential decay with lifetime equal to 1.29 msec. The fabricated materials can be used as a deep-red radiation light source for plant growth cultivation. (C) 2022 Optica Publishing Group under the terms of the Optica Open Access Publishing Agreement
引用
收藏
页码:2072 / 2086
页数:15
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