Sulfated polyborate: A mild, efficient catalyst for synthesis of N-tert-butyl/N-trityl protected amides via Ritter reaction

被引：38
作者：
Indalkar, Krishna S. [1 ]
Khatri, Chetan K. [1 ]
Chaturbhuj, Ganesh U. [1 ]
机构：
[1] Inst Chem Technol, Dept Pharmaceut Sci & Technol, Bombay 400019, Maharashtra, India
来源：
JOURNAL OF CHEMICAL SCIENCES | 2017年 / 129卷 / 04期
关键词：
Ritter reaction; sulfated polyborate; N-tert-butyl amide; solvent-free condition; ONE-POT SYNTHESIS; SUBSTITUTED AMIDES; SELECTIVE AMIDATION; ACID; NITRILES; ALCOHOLS; SOLVENT; CONVERSION; REARRANGEMENT;
D O I：
10.1007/s12039-017-1257-7
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Rapid, efficient and inexpensive method for synthesis of N-tert-butyl/N-trityl protected amides via Ritter reaction of nitriles with tertiary alcohols in the presence of a sulfated polyborate catalyst under solvent-free conditions is described. The catalyst has the advantage of Lewis as well as Bronsted acidity and recyclability without significant loss in catalytic activity along with easy work-up, short reaction time and good to excellent yields.
引用
收藏
页码：415 / 420
页数：6
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