Sulfated polyborate: A mild, efficient catalyst for synthesis of N-tert-butyl/N-trityl protected amides via Ritter reaction

被引：39

作者：

Indalkar, Krishna S. ^{[1
]}

Khatri, Chetan K. ^{[1
]}

Chaturbhuj, Ganesh U. ^{[1
]}

机构：

[1] Inst Chem Technol, Dept Pharmaceut Sci & Technol, Bombay 400019, Maharashtra, India

来源：

JOURNAL OF CHEMICAL SCIENCES | 2017年 / 129卷 / 04期

关键词：

Ritter reaction; sulfated polyborate; N-tert-butyl amide; solvent-free condition; ONE-POT SYNTHESIS; SUBSTITUTED AMIDES; SELECTIVE AMIDATION; ACID; NITRILES; ALCOHOLS; SOLVENT; CONVERSION; REARRANGEMENT;

D O I：

10.1007/s12039-017-1257-7

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rapid, efficient and inexpensive method for synthesis of N-tert-butyl/N-trityl protected amides via Ritter reaction of nitriles with tertiary alcohols in the presence of a sulfated polyborate catalyst under solvent-free conditions is described. The catalyst has the advantage of Lewis as well as Bronsted acidity and recyclability without significant loss in catalytic activity along with easy work-up, short reaction time and good to excellent yields.

引用

页码：415 / 420

页数：6

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