Polymerisation of olefins catalysed by a palladium complex in supercritical carbon dioxide

被引：32
作者：
de Vries, TJ
Duchateau, R
Vorstman, MAG
Keurentjes, JTF
机构：
[1] Eindhoven Univ Technol, Dept Chem & Chem Engn, Proc Dev Grp, NL-5600 MB Eindhoven, Netherlands
[2] Dutch Polymer Inst, NL-5600 AX Eindhoven, Netherlands
[3] Eindhoven Univ Technol, Schuit Inst Catalysis, NL-5600 MB Eindhoven, Netherlands
来源：
CHEMICAL COMMUNICATIONS | 2000年 / 04期
关键词：
D O I：
10.1039/a908966g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A late transition metal catalyst has been used to polymerise hex-1-ene and ethene in supercritical carbon dioxide, yielding high molecular weight polymers; a comparison with polymerisations in CH2Cl2 reveal that polymers with identical molecular weight and polydispersity are formed.
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页码：263 / 264
页数：2
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