Phase transition behavior of Ba(Mg1/3Nb2/3)O3 modified PbZrO3 solid solution

被引：24

作者：

Sukkha, Usa ^{[1
,3
]}

Vittayakorn, Naratip ^{[1
,2
,3
]}

Guo, Ruyan ^{[4
]}

Bhalla, Amar S. ^{[4
]}

机构：

[1] King Mongkuts Inst Technol Ladkrabang, Coll Nanotechnol, Electroceram Res Lab, Bangkok 10520, Thailand

[2] King Mongkuts Inst Technol Ladkrabang, Fac Sci, Dept Chem, Bangkok 10520, Thailand

[3] King Mongkuts Inst Technol Ladkrabang, Fac Sci, Adv Mat Res Unit, Bangkok 10520, Thailand

[4] Univ Texas San Antonio, Coll Engn, Dept Elect & Comp Engn, San Antonio, TX 78256 USA

来源：

JOURNAL OF MATERIALS CHEMISTRY C | 2014年 / 2卷 / 16期

基金：

美国国家科学基金会;

关键词：

ANTIFERROELECTRIC LEAD ZIRCONATE; MICROWAVE DIELECTRIC-PROPERTIES; ELECTRICAL-PROPERTIES; THERMAL-PROPERTIES; KINETICS; MICROSTRUCTURES; DECOMPOSITION; POLARIZATION; SITE;

D O I：

10.1039/c3tc32353f

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Different compositions of (1 - x)PbZrO3-xBa(Mg1/3Nb2/3)O-3 (PZ-BMN) system, with x = 0.00-0.50, were synthesized using the columbite precursor method. The effects of BMN content on phase transition, electrical and thermal properties of PbZrO3 ceramic were investigated. The composition range and stability of the ferroelectric phase in perovskite PZ-BMN system can be improved by optimizing BMN substitution. Phase transition behavior of various solid solutions of PZ compositions can be predicted by a phase diagram established from the average electronegativity difference versus tolerance factor of the end members.

引用

页码：2929 / 2938

页数：10

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