Tetrakis(triphenylarsine)silver(I) hexafluoro-phosphate

被引：3

作者：

Meijboom, Reinout ^{[1
]}

van Rensburg, J. Marthinus Janse ^{[1
]}

Kirsten, Leo ^{[1
]}

Viljoen, J. Augustinus ^{[1
]}

机构：

[1] Univ Orange Free State, Dept Chem, ZA-9300 Bloemfontein, South Africa

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2006年 / 62卷

关键词：

LEWIS-BASE ADDUCTS; METAL(I) COMPOUNDS; CRYSTAL-STRUCTURES; SILVER(I); COMPLEXES; TETRAKIS(TRIPHENYLPHOSPHINE)-SILVER(I); COORDINATION; PERCHLORATES; COPPER(I);

D O I：

10.1107/S1600536806036373

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Ag(AsC18H15)(4)]PF6, crystallizes with the cation on a threefold rotation axis and the anions on positions with site symmetry (3) over bar. The Ag atom is surrounded by four arsine ligands forming a distorted tetrahedral configuration. The Ag-As distances are 2.6381 (6) and 2.6499 (9) angstrom, and the As-Ag-As angles are 108.91 (1) and 110.03 (1)degrees.

引用

页码：M2567 / M2569

页数：3

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