Tetrakis(triphenylarsine)silver(I) hexafluoro-phosphate

被引：3
|
作者：
Meijboom, Reinout [1 ]
van Rensburg, J. Marthinus Janse [1 ]
Kirsten, Leo [1 ]
Viljoen, J. Augustinus [1 ]
机构：
[1] Univ Orange Free State, Dept Chem, ZA-9300 Bloemfontein, South Africa
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2006年 / 62卷
关键词：
LEWIS-BASE ADDUCTS; METAL(I) COMPOUNDS; CRYSTAL-STRUCTURES; SILVER(I); COMPLEXES; TETRAKIS(TRIPHENYLPHOSPHINE)-SILVER(I); COORDINATION; PERCHLORATES; COPPER(I);
D O I：
10.1107/S1600536806036373
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Ag(AsC18H15)(4)]PF6, crystallizes with the cation on a threefold rotation axis and the anions on positions with site symmetry (3) over bar. The Ag atom is surrounded by four arsine ligands forming a distorted tetrahedral configuration. The Ag-As distances are 2.6381 (6) and 2.6499 (9) angstrom, and the As-Ag-As angles are 108.91 (1) and 110.03 (1)degrees.
引用
收藏
页码：M2567 / M2569
页数：3
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