Metal Free Conducting PEDOS, PEDOT, and Their Analogues via an Unusual Bromine-Catalyzed Polymerization

被引：39

作者：

Patra, Asit ^{[1
,2
]}

Agrawal, Vikash ^{[1
]}

Bhargav, Ranoo ^{[1
]}

Shahjad ^{[1
]}

Bhardwaj, Dinesh ^{[1
]}

Chand, Suresh ^{[1
]}

Sheynin, Yana ^{[2
]}

Bendikov, Michael ^{[2
]}

机构：

[1] Acad Sci & Innovat Res AcSIR, Organ & Hybrid Solar Cells Grp, Natl Phys Lab, CSIR,Network Inst Solar Energy, New Delhi 110012, India

[2] Weizmann Inst Sci, Dept Organ Chem, IL-76100 Rehovot, Israel

来源：

MACROMOLECULES | 2015年 / 48卷 / 24期

关键词：

SOLID-STATE SYNTHESIS; BUILDING-BLOCK; POLYMERS; NUCLEI;

D O I：

10.1021/acs.macromol.5b01777

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new molecular Br-2-catalyzed polymerization of 2,5-dibromo-3,4,ethylenedioicyselenophene (DBEDOS), 2,5-rdibromo-3,4-ethylenedioxythiophene (DEEDOT), and their analogues, providing metal free and virtually defect free conducting polymers under mild reaction conditions. The resulting poly(3,4-ethylenedioxyserenophene) (PEDOS), poly(3,4-ethylenedipxythiophene) (PEDOT) and their analogues are electroactive, highly conducting and shown optoelectronic properties practically identical to electrochemically prepared insoluble thin films. This polymerization is a rare example of metal free polymerization which lead to the formation of conjugated polymer. Details characterizations of the obtained polymers were carried out and spectra electrochemistry of PEDOS-C-12 film obtained by Br-2-catalyzed polymerization suggest higher Conductivity and trarisparency coil-Tared to -PEDOS-C-12 film obtained by other methods.

引用

页码：8760 / 8764

页数：5

共 41 条

[1]

[Anonymous], HDB CONDUCTING POLYM

[2]

[Anonymous], ADV MAT

[3]

[Anonymous], HDB CONDUCTING POLYM

[4] Synthesis of 3,4-ethylenedioxyselenophene (EDOS):: A novel building block for electron-rich π-conjugated polymers [J].