Synthesis of palladium (II) complexes of N-p-iodophenyl substituted 1,5-diaza-3,7-diphosphacyclooctanes

被引：1

作者：

Dayanova, Irina ^{[1
]}

Khabibullin, Roman ^{[1
]}

Strelnik, Igor ^{[1
]}

Musina, Elvira ^{[1
]}

Karasik, Andrey ^{[1
]}

Sinyashin, Oleg ^{[1
]}

机构：

[1] RAS, FRC Kazan Sci Ctr, AE Arbuzov Inst Organ & Phys Chem, Kazan 420088, Russia

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2019年 / 194卷 / 4-6期

关键词：

Coordination chemistry; cyclic aminomethylphosphines; palladium(II) complex; 1; 5-diaza-3; 7-diphosphacyclooctanes; LIGANDS;

D O I：

10.1080/10426507.2018.1541241

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The 1,5-di(p-iodophenyl)-3,7-bis(pyrid-2-)yl-1,5-diaza-3,7-diphosphacyclooctane was obtained via reaction of pyridylphosphine, paraformaldehyde and 4-iodoaniline. The ligand reacts with Pd(COD)Cl-2 to form bischelate cationic Pd(II) or monochelate neutral Pd(II) complexes depending on a ligand-metal ratio. The structures of new ligand and both complexes were confirmed by NMR-spectroscopy, mass-spectrometry and elemental analysis. [GRAPHICS] .

引用

页码：515 / 516

页数：2

共 27 条

[21] Synthesis, crystal structures, DNA-binding properties, cytotoxic and antioxidation activities of several new ternary copper(II) complexes of N,N′-(p-xylylene)di-alanine acid and 1,10-phenanthroline [J].

Jia, Lei ;

Jiang, Peng ;

Xu, Jun ;

Hao, Zhong-yan ;

Xu, Xi-ming ;

Chen, Long-hai ;

Wu, Jin-cai ;

Tang, Ning ;

Wang, Qin ;

Vittal, Jagadese J. .

INORGANICA CHIMICA ACTA, 2010, 363 (05) :855-865

[22] Synthesis and antiproliferative activity of the heterobimetallic complexes [RuClCp(PPh3)-μ-dmoPTA-1κP:2κ2N,N′-MCl2] (M = Co, Ni, Zn; dmoPTA=3,7-dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane) [J].

Serrano-Ruiz, Manuel ;

Manuel Aguilera-Saez, Luis ;

Lorenzo-Luis, Pablo ;

Padron, Jose M. ;

Romerosa, Antonio .

DALTON TRANSACTIONS, 2013, 42 (31) :11212-11219

[23] Synthesis and reactivity studies of palladium(II) complexes containing the N-phosphorylated iminophosphorane-phosphine ligands Ph2PCH2P{=NP(=O)(OR)2}Ph2 (R = Et, Ph):: application to the catalytic synthesis of 2,3-dimethylfuran [J].

Cadierno, Victorio ;

Diez, Josefina ;

Garcia-Alvarez, Joaquin ;

Gimeno, Jose ;

Nebra, Noel ;

Rubio-Garcia, Javier .

DALTON TRANSACTIONS, 2006, (47) :5593-5604

[24] Synthesis and characterization of new (N-diphenylphosphino)-isopropylanilines and their complexes: crystal structure of (Ph2P=S)NH-C6H4-4-CH(CH3)2 and catalytic activity of palladium(II) complexes in the Heck and Suzuki cross-coupling reactions [J].

Aydemir, Murat ;

Baysal, Akin ;

Gurbuz, Nevin ;

Ozdemir, Ismail ;

Gumgum, Bahattin ;

Ozkar, Saim ;

Caylak, Nagihan ;

Yildirim, Leyla Tatar .

APPLIED ORGANOMETALLIC CHEMISTRY, 2010, 24 (01) :17-24

[25] New hexaphosphane ligands 1,3,5-C6H3{p-C6H4N(PX2)2}3 [ X = Cl, F, C6H3OMe(C3H5)]: Synthesis, derivatization and palladium(II) and platinum(II) complexes [J].

Rao, Sowmya ;

Ganesamoorthy, Chelladurai ;

Mobin, Shaikh M. ;

Balakrishna, Maravanji S. .

DALTON TRANSACTIONS, 2011, 40 (22) :5841-5843

[26] Synthesis and Characterization of New Palladium(II) Complexes Containing N-Alkylamino-3,5-diphenylpyrazole Ligands. Crystal Structure of [PdCl(L2)](BF4) {L2=Bis[2-(3,5-diphenyl-1-pyrazolyl)ethyl]ethylamine} [J].

Aragay, Gemma ;

Pons, Josefina ;

Garcia-Anton, Jordi ;

Mendoza, Angeles ;

Mendoza-Diaz, Guillermo ;

Calvet, Teresa ;

Font-Bardia, Merce ;

Ros, Josep .

AUSTRALIAN JOURNAL OF CHEMISTRY, 2009, 62 (05) :475-482

[27] SYNTHESIS, STRUCTURE, AND CYTOTOXICITY EVALUATION OF PALLADIUM(II) COMPLEXES OF 4-AMINO-3-HYDRAZINO-1,2,4-TRIAZIN-5(4H)-ONES AND 4-AMINO-3-(N-METHYLHYDRAZINO)-1,2,4-TRIAZIN-5(4H)-ONES [J].

BORRELL, JI ;

VICTORY, P ;

BETI, C ;

BATLLORI, X ;

SCHAEIDT, H ;

GIMENEZPEREZ, O ;

TEXIDO, J ;

SERRA, B ;

SOLANS, X ;

FONTBARDIA, M .

ANALES DE QUIMICA, 1995, 91 (3-4) :243-252

← 1 2 3 →