Synthesis of palladium (II) complexes of N-p-iodophenyl substituted 1,5-diaza-3,7-diphosphacyclooctanes

被引：1

作者：

Dayanova, Irina ^{[1
]}

Khabibullin, Roman ^{[1
]}

Strelnik, Igor ^{[1
]}

Musina, Elvira ^{[1
]}

Karasik, Andrey ^{[1
]}

Sinyashin, Oleg ^{[1
]}

机构：

[1] RAS, FRC Kazan Sci Ctr, AE Arbuzov Inst Organ & Phys Chem, Kazan 420088, Russia

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2019年 / 194卷 / 4-6期

关键词：

Coordination chemistry; cyclic aminomethylphosphines; palladium(II) complex; 1; 5-diaza-3; 7-diphosphacyclooctanes; LIGANDS;

D O I：

10.1080/10426507.2018.1541241

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The 1,5-di(p-iodophenyl)-3,7-bis(pyrid-2-)yl-1,5-diaza-3,7-diphosphacyclooctane was obtained via reaction of pyridylphosphine, paraformaldehyde and 4-iodoaniline. The ligand reacts with Pd(COD)Cl-2 to form bischelate cationic Pd(II) or monochelate neutral Pd(II) complexes depending on a ligand-metal ratio. The structures of new ligand and both complexes were confirmed by NMR-spectroscopy, mass-spectrometry and elemental analysis. [GRAPHICS] .

引用

页码：515 / 516

页数：2

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