Charge-transfer in a π-stacked fullerene porphyrin dyad:: evidence for back electron transfer in the 'Marcus-inverted' region

被引：117

作者：

Guldi, DM ^{[1
]}

Luo, CP

Prato, M

Dietel, E

Hirsch, A

机构：

[1] Univ Notre Dame, Radiat Lab, Notre Dame, IN 46556 USA

[2] Univ Trieste, Dipartimento Sci Farmaceut, I-34127 Trieste, Italy

[3] Univ Erlangen Nurnberg, Inst Organ Chem, D-91054 Erlangen, Germany

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 05期

关键词：

D O I：

10.1039/a909657d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The 'Marcus-inverted' region for BET in a pi-pi stacked fullerene-porphyrin dyad was determined based on (i) the photoactivation of an intramolecular ET in a variety of solvents and (ii) the formation of a highly energetic charge-separated state.

引用

页码：373 / 374

页数：2

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