Charge-transfer in a π-stacked fullerene porphyrin dyad:: evidence for back electron transfer in the 'Marcus-inverted' region

被引:116
作者
Guldi, DM [1 ]
Luo, CP
Prato, M
Dietel, E
Hirsch, A
机构
[1] Univ Notre Dame, Radiat Lab, Notre Dame, IN 46556 USA
[2] Univ Trieste, Dipartimento Sci Farmaceut, I-34127 Trieste, Italy
[3] Univ Erlangen Nurnberg, Inst Organ Chem, D-91054 Erlangen, Germany
关键词
D O I
10.1039/a909657d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The 'Marcus-inverted' region for BET in a pi-pi stacked fullerene-porphyrin dyad was determined based on (i) the photoactivation of an intramolecular ET in a variety of solvents and (ii) the formation of a highly energetic charge-separated state.
引用
收藏
页码:373 / 374
页数:2
相关论文
共 21 条