Sn-doped TiO2 nanorod arrays and application in perovskite solar cells

被引:92
作者
Zhang, Xiang [1 ]
Bao, Zhongqiu [1 ]
Tao, Xiyun [1 ]
Sun, Hongxia [1 ]
Chen, Wen [1 ]
Zhou, Xingfu [1 ]
机构
[1] Nanjing Univ Technol, Coll Chem & Chem Engn, State Key Lab Mat Oriented Chem Engn, Nanjing 210009, Jiangsu, Peoples R China
来源
RSC ADVANCES | 2014年 / 4卷 / 109期
关键词
HOLE CONDUCTOR; EFFICIENCY; CH3NH3PBI3; PERFORMANCE; DEPOSITION; REACTIVITY; TRANSPORT;
D O I
10.1039/c4ra11155a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Tin-doped (Sn-doped) TiO2 nanorods arrays were successfully synthesized on a TiO2 seed layer via a mild one-pot hydrothermal method. Sn-doped TiO2 nanorods with high electron mobility were assembled into a solid perovskite solar cell. The study indicated that the introduction of the Sn element led to the change of the TiO2 band gap from 3.0 to 3.04 eV. Electrochemical impedance spectroscopy showed that the resistance of the device based on Sn-doped TiO2 nanorods was lower than that of the undoped device. The PCE of the Sn-doped perovskite device achieved 6.31%, which was almost 67% higher than that of the undoped sample.
引用
收藏
页码:64001 / 64005
页数:5
相关论文
共 50 条
[31]   Preparation and characterization of dye-sensitized TiO2 nanorod solar cells [J].
Meng, Lijian ;
Chen, Hong ;
Li, Can ;
dos Santos, M. P. .
THIN SOLID FILMS, 2015, 577 :103-108
[32]   ZnS passivated PbSe sensitized TiO2 nanorod arrays to suppress photocorrosion in photoelectrochemical solar cells [J].
Bhat, T. S. ;
Mali, S. S. ;
Sheikh, A. D. ;
Tarwal, N. L. ;
Korade, S. D. ;
Hong, C. K. ;
Kim, J. H. ;
Patil, P. S. .
MATERIALS TODAY COMMUNICATIONS, 2018, 16 :186-193
[33]   Boosting the power conversion efficiency of perovskite solar cells based on Sn doped TiO2 electron extraction layer via modification the TiO2 phase junction [J].
Liao, Ying-Han ;
Chang, Yin-Hsuan ;
Lin, Ting-Han ;
Chan, Shun-Hsiang ;
Lee, Kun-Mu ;
Hsu, Kai-Hsiang ;
Hsu, Jen-Fu ;
Wu, Ming-Chung .
SOLAR ENERGY, 2020, 205 :390-398
[34]   Preparation of Crystalline Sn-Doped TiO2 and Its Application in Visible-Light Photocatalysis [J].
Zhou Xiufeng ;
Lu Juan ;
Li Lianghai ;
Wang Zuoshan .
JOURNAL OF NANOMATERIALS, 2011, 2011
[35]   TiO2 Nanocolumn Arrays for More Efficient and Stable Perovskite Solar Cells [J].
Hu, Zhelu ;
Miguel Garcia-Martin, Jose ;
Li, Yajuan ;
Billot, Laurent ;
Sun, Baoquan ;
Fresno, Fernando ;
Garcia-Martin, Antonio ;
Ujue Gonzalez, Maria ;
Aigouy, Lionel ;
Chen, Zhuoying .
ACS APPLIED MATERIALS & INTERFACES, 2020, 12 (05) :5979-5989
[36]   Enhanced power conversion efficiency of inverted organic solar cells by using solution processed Sn-doped TiO2 as an electron transport layer [J].
Thambidurai, M. ;
Kim, Jun Young ;
Song, Hyung-jun ;
Ko, Youngjun ;
Muthukumarasamy, N. ;
Velauthapillai, Dhayalan ;
Bergmann, Victor W. ;
Weber, Stefan A. L. ;
Lee, Changhee .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (29) :11426-11431
[37]   Facile synthesis of ordered Nb2O5 coated TiO2 nanorod arrays for efficient perovskite solar cells [J].
Li, Rui ;
Huo, Xiangtao ;
Han, Xing ;
Wang, Zhipeng ;
Zhang, Mei ;
Guo, Min .
APPLIED SURFACE SCIENCE, 2021, 542
[38]   Rutile TiO2 nanowire-based perovskite solar cells [J].
Jiang, Qinglong ;
Sheng, Xia ;
Li, Yingxuan ;
Feng, Xinjian ;
Xu, Tao .
CHEMICAL COMMUNICATIONS, 2014, 50 (94) :14720-14723
[39]   Electrochemical formation of TiO2 porous layer for perovskite solar cells [J].
Anuratha, Krishnan Shanmugam ;
Peng, Hsiao-Shan ;
Hsieh, Chien-Kuo ;
Xiao, Yaoming ;
Lin, Jeng-Yu .
THIN SOLID FILMS, 2018, 660 :720-724
[40]   Properties of Perovskite Solar Cells by the Sputtered Compact TiO2 Layer [J].
Shin, Seong Gwan ;
Bark, Chung Wung ;
Kim, Sang Mo ;
Choi, Hyung Wook .
SCIENCE OF ADVANCED MATERIALS, 2017, 9 (09) :1517-1521