New epoxy-unsaturated polyester resin copolymers

被引:14
作者
Brzozowski, ZK [1 ]
Szymanska, E [1 ]
Bratychak, MM [1 ]
机构
[1] STATE UNIV LVIVSKA PILITECHN,LVOV,UKRAINE
关键词
epoxy; polyester; fire-retardance; copolymer;
D O I
10.1016/S1381-5148(97)00045-X
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Some fire-resistant epoxy resins known in literature and practice were reviewed. New unsaturated polyester resins with decreasing flammability was reviewed. The main monomers were dibromobutendiol and diallylic ether of dibromoneopentylglycol. The new idea of epoxy resin fire-retardance by creating new epoxy resin-unsaturated polyester copolymers was put forward and then obtained. The reagents were as follows: low-molecular epoxy resin, polyamine curing agent, special diazo-epoxy resin, brominated unsaturated polyester resins, styrene or diallylic ether of dibromoneopentylglycol as diluent to obtain optimum viscosity. The proposed mechanism to form three-dimensional copolymer network was presented.
引用
收藏
页码:217 / 224
页数:8
相关论文
共 15 条
[1]  
BRATYCHAK MM, 1997, IN PRESS J APPL POLY
[2]  
BRATYCHAK MM, 1982, Patent No. 973546
[3]   PROPERTIES OF ELASTOMERS CROSSLINKED BY BISGLYCIDYL ETHER OF 2,2-BIS (PARA-HYDROXYPHENYL)-1,1,1-TRICHLOROETHANE [J].
BRZOZOWSKI, ZK ;
GAJEWSKI, M ;
BRZEZINSKI, Z .
JOURNAL OF APPLIED POLYMER SCIENCE, 1977, 21 (07) :1783-1793
[4]   UNSATURATED RESINS OBTAINED FROM BISPHENOLS AND GLICYDYL ESTERS OF ACRYLIC ACIDS [J].
BRZOZOWSKI, ZK ;
NOWICKI, A .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1975, 13 (06) :1479-1487
[5]  
BRZOZOWSKI ZK, 1996, NEW SPECIAL COPOLYME
[6]  
BRZOZOWSKI ZK, 1988, Patent No. 276098
[7]  
BRZOZOWSKI ZK, 1995, POLYM POLYM COMPOS, V3, P1
[8]  
BRZOZOWSKI ZK, 1994, MACROMOL REPORTS A, V31, P643
[9]  
BRZOZOWSKI ZK, 1995, Patent No. 311834
[10]  
BRZOZOWSKI ZK, 1986, THESIS WARSAW U TECH, P50