Morphology of the nanocellulose produced by periodate oxidation and reductive treatment of cellulose fibers

被引:67
作者
Errokh, Amira [1 ]
Magnin, Albert [2 ]
Putaux, Jean-Luc [3 ]
Boufi, Sami [1 ]
机构
[1] Univ Sfax, LMSE, Fac Sci, BP 802-3018, Sfax, Tunisia
[2] Univ Grenoble Alpes, CNRS, LRP, Grenoble 38000, France
[3] Univ Grenoble Alpes, CNRS, CERMAV, F-38000 Grenoble 38000, France
关键词
Nanocellulose; Periodate; Oxidation; Aldehyde; STABILIZED NANOCRYSTALLINE CELLULOSE; NANOFIBRILS; AMINATION;
D O I
10.1007/s10570-018-1871-7
中图分类号
TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];
学科分类号
0805 ; 080502 ; 0822 ;
摘要
Nanocellulose with a morphology ranging from long flexible to rod-like fibrils were produced via periodate oxidation route followed by reductive treatment with NaBH4 of never-dried eucalyptus pulp. The effect of the aldehyde content on the size and morphology of the resulting nanocellulose was studied by preparing three samples with 450, 830 and 1480 A mu mol g(-1) aldehyde content. The change in particle size after the oxidation and reduction was monitored by dynamic light scattering and the morphology of the nanocellulose was characterized by transmission electron microscopy. It was shown that the length of the cellulose fibrils significantly decreased with increasing oxidation. Depending on the aldehyde content, elementary nanofibrils or bundles of nanofibrils with a length from 100 nm up to several A mu m were obtained after the reduction process. The reinforcing potential of the nanocellulose was also investigated by dynamic thermomechanical analysis of nanocomposite films with different nanocellulose contents. [GRAPHICS] .
引用
收藏
页码:3899 / 3911
页数:13
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