Discrete metal complexes of two multiply armed ligands

被引：26

作者：

Al-Mandhary, Muna R. A.

Fitchett, Christopher M.

Steel, Peter J. ^{[1
]}

机构：

[1] Univ Canterbury, Dept Chem, Christchurch 8020, New Zealand

[2] Sultan Qaboos Univ, Coll Sci, Al Khoud 123, Oman

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2006年 / 59卷 / 05期

关键词：

D O I：

10.1071/CH06116

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The syntheses and metal complexes of 1,2,4,5-tetrakis(8-quinolyloxymethyl) benzene 1 and hexakis(8-quinolyloxymethyl) benzene 2 are described. X-Ray crystal structures are reported of the free ligand 1, a binuclear silver(I) and a tetranuclear copper(I) complex of 1, as well as a binuclear cobalt(II) and trinuclear palladium(II) and silver(I) complexes of 2. Within these discrete metal complexes the ligands are found to adopt a range of coordination modes, with considerable variation in the relative orientations of the ligand arms as a result of the flexibility imparted by the CH2O linker units.

引用

页码：307 / 314

页数：8

共 60 条

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