Efficient selective synthesis of 2-substituted indoles from complex-base-promoted arynic cyclisations

被引：9
作者：
KuehmCaubere, C
Rodriguez, I
Pfeiffer, B
Renard, P
Caubere, P
机构：
[1] UNIV NANCY 1,FAC SCI,LAB CHIM ORGAN 1,CNRS,URA 457,F-54506 VANDOEUVRE NANCY,FRANCE
[2] ADIR,F-92415 COURBEVOIE,FRANCE
来源：
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1997年 / 19期
关键词：
D O I：
10.1039/a702548c
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
2-Substituted indoles have been efficiently obtained by selective arynic cyclisation of halogenated aryl imines of methyl ketones in the presence of the complex-base NaNH2-(BuONa)-O-t and by PhCH2SH-AlCl3 opening of tetrahydrothiopyranoindoles also obtained from arynic cyclisation of imines.
引用
收藏
页码：2857 / 2862
页数：6
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