Effect of surface finishing on the oxidation behaviour of a ferritic stainless steel

被引:19
作者
Ardigo-Besnard, M. R. [1 ]
Popa, I. [1 ]
Heintz, O. [1 ]
Chassagnon, R. [1 ]
Vilasi, M. [2 ]
Herbst, F. [1 ]
Girardon, P. [3 ]
Chevalier, S. [1 ]
机构
[1] Univ Bourgogne Franche Comte, Lab Interdisciplinaire Carnot Bourgogne ICB, UMR 6303, CNRS, BP 47870, F-21078 Dijon, France
[2] Univ Lorraine, UMR 7198, Inst Jean Lamour, CNRS, Parc Saurupt, F-54011 Nancy, France
[3] APERAM, Ctr Rech, BP15, F-62330 Isbergues, France
关键词
Stainless steel; Surface finishing; Oxidation; Microstructure; Residual stress; HIGH-TEMPERATURE OXIDATION; WATER-VAPOR; SELECTIVE OXIDATION; CHROMIA SCALES; GRAIN-SIZE; MECHANISMS; ALLOYS; GROWTH; METALS; HYDROGEN;
D O I
10.1016/j.apsusc.2017.03.280
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The corrosion behaviour and the oxidation mechanism of a ferritic stainless steel, K41X (AISI 441), were evaluated at 800 degrees C in water vapour hydrogen enriched atmosphere. Mirror polished samples were compared to as-rolled K41X material. Two different oxidation behaviours were observed depending on the surface finishing: a protective double (Cr,Mn)(3)O-4/Cr2O3 scale formed on the polished samples whereas external Fe3O4 and (Cr,Fe)(2)O-3 oxides grew on the raw steel. Moreover, isotopic marker experiments combined with SIMS analyses revealed different growth mechanisms. The influence of surface finishing on the corrosion products and growth mechanisms was apprehended by means of X-ray photoelectron spectroscopy (XPS) and residual stress analyses using XRD at the sample surfaces before ageing. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:196 / 206
页数:11
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