Biodiesel production from tobacco (Nicotiana tabacum L.) seed oil with a high content of free fatty acids

被引:291
作者
Veljkovic, V. B. [1 ]
Lakicevic, S. H. [1 ]
Stamenkovic, O. S. [1 ]
Todorovic, Z. B. [1 ]
Lazic, M. L. [1 ]
机构
[1] Fac Technol, Leskovac, Serbia
关键词
biodiesel; methanolysis; tobacco seed oil;
D O I
10.1016/j.fuel.2006.04.015
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The production of fatty acid methyl esters (FAME) from crude tobacco seed oil (TSO) having high free fatty acids (FFA) was investigated. Due to its high FFA, the TSO was processed in two steps: the acid-catalyzed esterification (ACE) followed by the base-catalyzed methanolysis (BCM). The first step reduced the FFA level to less than 2% in 25 min for the molar ratio of 18:1. The second step converted the product of the first step into FAME and glycerol. The maximum yield of FAME was about 91% in about 30 min. The tobacco biodiesel obtained had the fuel properties within the limits prescribed by the latest American (ASTM D 6751-02) and European (DIN EN 14214) standards, except a somewhat higher acid value than that prescribed by the latter standard (< 0.5). Thus, tobacco seeds (TS), as agricultural wastes, might be a valuable renewable raw material for the biodiesel production. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2671 / 2675
页数:5
相关论文
共 10 条
[1]  
Canakci M, 2001, T ASAE, V44, P1429, DOI 10.13031/2013.7010
[2]  
ESHETU B, 2005, NICOTIANA TABACUM 6
[3]   Biodiesel production from mahua (Madhuca indica) oil having high free fatty acids [J].
Ghadge, SV ;
Raheman, H .
BIOMASS & BIOENERGY, 2005, 28 (06) :601-605
[4]   Tobacco seed oil as an alternative diesel fuel: physical and chemical properties [J].
Giannelos, PN ;
Zannikos, F ;
Stournas, S ;
Lois, E ;
Anastopoulos, G .
INDUSTRIAL CROPS AND PRODUCTS, 2002, 16 (01) :1-9
[5]  
Holcapek M, 1999, J CHROMATOGR A, V858, P13
[6]  
*ISO, 1983, 660 ISO
[7]   Biodiesel production from high FFA rubber seed oil [J].
Ramadhas, AS ;
Jayaraj, S ;
Muraleedharan, C .
FUEL, 2005, 84 (04) :335-340
[8]  
STANISAVLJEVIC IT, 2005, SEECCHE, V1, P67
[9]  
Trajkovic J.E. A., 1983, Food analysis
[10]   Use of tobacco seed oil methyl ester in a turbocharged indirect injection diesel engine [J].
Usta, N .
BIOMASS & BIOENERGY, 2005, 28 (01) :77-86