Preparation and characterization of highly mesoporous activated short carbon fibers from kenaf precursors

被引:21
作者
Baek, Jin [1 ]
Lee, Hye-Min [1 ,2 ]
An, Kay-Hyeok [3 ]
Kim, Byung-Joo [1 ]
机构
[1] Korea Inst Carbon Convergence Technol, Res Lab Multifunct Carbon Mat, Jeonju 54853, South Korea
[2] Inha Univ, Dept Chem, Incheon 22212, South Korea
[3] Jeonju Univ, Dept Carbon & Nano Mat Engn, Jeonju 55069, South Korea
关键词
Activation; Kenaf; Mesopore fraction; Specific surface area; SURFACE-AREA; PERFORMANCE; ADSORPTION; PYROLYSIS; CELLULOSE; ELECTRODE;
D O I
10.1007/s42823-019-00042-y
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this study, activated carbon with well-developed mesopores was fabricated using kenaf short fibers as a representative biomass. Concentrated phosphoric acid was selected as an activation agent to create highly developed porous structures, and pore development was observed to occur in relation to the weight ratio of phosphoric acid and kenaf. The pore characteristics of the kenaf-based activated carbon were determined using the N-2/77K adsorption isotherm, and its microcrystalline structure was analyzed using X-ray diffraction. The highest specific surface area (1570 m(2)/g) was observed when the weight ratio of phosphoric acid to kenaf was 3:1, and the highest mesopore fraction (74%) was observed at 4:1. The carbonization yield was 45-35%, which is higher than that of commercial activated carbon. The production of porous carbon material by this method offers high potential for application because it can be controlled over a wide range of average pore diameter from 2.48 to 5.44 nm.
引用
收藏
页码:393 / 399
页数:7
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