Catalytic Wet Oxidation of Pharmaceutical Sludge by Molecular Sieve Loaded with Cu/Ce

被引:18
|
作者
Zeng, Xu [1 ]
Liu, Jun [1 ,2 ]
Zhao, Jianfu [1 ]
机构
[1] Tongji Univ, Coll Environm Sci & Engn, State Key Lab Pollut Control & Resources Reuse, 1239 Siping Rd, Shanghai 200092, Peoples R China
[2] Shanghai Elect Power Generatoin Environm Protect, Shanghai 201612, Peoples R China
来源
CATALYSTS | 2018年 / 8卷 / 02期
关键词
pharmaceutical sludge; wet oxidation; molecular sieve; chemical oxygen demand; volatile suspended solids; HYDROGEN-PEROXIDE; AIR OXIDATION;
D O I
10.3390/catal8020067
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In the present study, the catalytic wet oxidation of pharmaceutical sludge by molecular sieve loaded with Cu/Ce as catalyst was investigated. Experiments were performed in an experimental batch reactor. Reaction parameters including catalyst dose, temperature, time, and oxygen pressure were discussed. The results showed that the catalysts prepared by co-precipitating method have good catalytic performance. Under optimum conditions, the highest volatile suspended solids (VSS) removal rate approximately 92% and chemical oxygen demand (COD) removal rate of 75% were obtained at 260 degrees C for 60 min with initial oxygen pressure 1.0 MPa and the catalyst 10 g/L. These results implied that the catalytic wet oxidation of pharmaceutical sludge by molecular sieve loaded with Cu/Ce is a promising method for the highly efficient degradation of the sludge.
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页数:8
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