Gas cell for in situ soft X-ray transmission-absorption spectroscopy of materials

被引：9

作者：

Drisdell, W. S. ^{[1
]}

Kortright, J. B. ^{[1
]}

机构：

[1] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Mat Sci, Berkeley, CA 94720 USA

来源：

REVIEW OF SCIENTIFIC INSTRUMENTS | 2014年 / 85卷 / 07期

关键词：

METAL-ORGANIC FRAMEWORKS; CARBON-DIOXIDE CAPTURE; FINE-STRUCTURE; DIFFRACTION; THICKNESS; CATALYSIS; SOLIDS; WATER;

D O I：

10.1063/1.4890816

中图分类号：

TH7 [仪器、仪表];

学科分类号：

0804 ; 080401 ; 081102 ;

摘要：

A simple gas cell design, constructed primarily from commercially available components, enables in situ soft X-ray transmission-absorption spectroscopy of materials in contact with gas at ambient temperature. The cell has a minimum X-ray path length of 1 mm and can hold gas pressures up to similar to 300 Torr, and could support higher pressures with simple modifications. The design enables cycling between vacuum and gas environments without interrupting the X-ray beam, and can be fully sealed to allow for measurements of air-sensitive samples. The cell can attach to the downstream port of any appropriate synchrotron beamline, and offers a robust and versatile method for in situ measurements of certain materials. The construction and operation of the cell are discussed, as well as sample preparation and proper spectral analysis, illustrated by examples of spectral measurements. Potential areas for improvement and modification for specialized applications are also mentioned. (C) 2014 AIP Publishing LLC.

引用

页数：7

共 31 条

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