Synthesis of new macrocyclic aminomethylphosphines based on 4,4′-diaminodiphenylmethane and its derivatives

被引：20

作者：

Kuznetsov, RM ^{[1
]}

Balueva, AS ^{[1
]}

Litvinov, IA ^{[1
]}

Gubaidullin, AT ^{[1
]}

Nikonov, GN ^{[1
]}

Karasik, AA ^{[1
]}

Sinyashin, OG ^{[1
]}

机构：

[1] Russian Acad Sci, Kazan Res Ctr, AE Arbuzov Organ & Phys Chem Inst, Kazan 420088, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2002年 / 51卷 / 01期

关键词：

macrocyclic aminomethylphosphines; X-ray diffraction analysis; 4,4 '-bis(hydroxymethyl)phenylphosphine; diaminodiphenylmethane;

D O I：

10.1023/A:1015086419302

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of bis(hydroxymethyl)phenylphosphine with 4,4'-diaminodiphenylmethane in DMF afforded 1,1',5,5'-bis[metylenedi(p-phenylene)]di(3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane) (1) whose structure was established by X-ray diffraction analysis. Sulfurization and oxidation of macrocyclic tetraphosphine 1 gave rise to products 2 and 3, respectively, compound 3 being obtained as a stable hexahydrate. The reaction of bis(hydroxymethyl)phenylphosphine with bis(4-N-methylaminophenyl)methane in DMF followed by sulfurization yielded monocyclic bis{methylenedi[p-phenylene(N-methyl)amino-methyl]}di(P-phenyl)phosphine sulfide (4).

引用

页码：151 / 156

页数：6

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