FTIR spectral analysis on heavy metal borate glasses

被引:17
作者
Karthikeyan, B. [1 ]
机构
[1] Raman Res Inst, Opt Grp, Bangalore 560080, Karnataka, India
来源
MODERN PHYSICS LETTERS B | 2006年 / 20卷 / 10期
关键词
oxide glasses; local structure; FTIR spectroscopy;
D O I
10.1142/S0217984906010688
中图分类号
O59 [应用物理学];
学科分类号
摘要
Inorganic heavy metal borate glasses were prepared through the melt quenching technique. Two sets of glasses were prepared, the compositions are (wt.%) 35Bi(2)O(3) + (50-x) B2O3 + 15Na(2)O + xPbO, where x = 0, 10, 20, 30 and 35MO + 30Na(2)O + 3513203 (MO = Bi2O3, PbO, ZnO). The FTIR structural analysis was made. These glasses have different borate groups and it mainly depends on the modifier/metal ion concentration. The influence of heavy metal and transition metal ion on the borate network were also identified.
引用
收藏
页码:533 / 538
页数:6
相关论文
共 15 条
[1]  
ADAMS RV, 1959, J SOC GLASS TECHNOL, V43, P147
[2]   Structural study of the Fe2O3-B2O3-BaO glass system by FTIR spectroscopy [J].
Ardelean, I ;
Toderas, M ;
Pascuta, P .
MODERN PHYSICS LETTERS B, 2003, 17 (22) :1175-1179
[3]  
BISAY A, 1969, PHYS CHEM GLASSES-B, V10, P1
[4]  
DUMBAUGH WH, 1986, PHYS CHEM GLASSES, V27, P119
[5]   NONLINEAR OPTICAL SUSCEPTIBILITIES OF HIGH-INDEX GLASSES [J].
HALL, DW ;
NEWHOUSE, MA ;
BORRELLI, NF ;
DUMBAUGH, WH ;
WEIDMAN, DL .
APPLIED PHYSICS LETTERS, 1989, 54 (14) :1293-1295
[6]   Z-scan analyses for PbO-containing glass with large optical nonlinearity [J].
Hashimoto, T ;
Yamamoto, T ;
Kato, T ;
Nasu, H ;
Kamiya, K .
JOURNAL OF APPLIED PHYSICS, 2001, 90 (02) :533-537
[7]   STRUCTURE AND PROPERTIES OF NONCONVENTIONAL GLASSES IN THE BINARY BISMUTH CUPRATE SYSTEM [J].
HAZRA, S ;
GHOSH, A .
PHYSICAL REVIEW B, 1995, 51 (02) :851-856
[8]   Properties of unconventional lithium bismuthate glasses [J].
Hazra, S ;
Mandal, S ;
Ghosh, A .
PHYSICAL REVIEW B, 1997, 56 (13) :8021-8025
[9]   IONIC-CONDUCTIVITY OF LI2O-B2O3 THIN-FILMS [J].
ITO, Y ;
MIYAUCHI, K ;
OI, T .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1983, 57 (03) :389-400
[10]   INFRARED REFLECTANCE SPECTRA OF LITHIUM BORATE GLASSES [J].
KAMITSOS, EI ;
PATSIS, AP ;
KARAKASSIDES, MA ;
CHRYSSIKOS, GD .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1990, 126 (1-2) :52-67