Environmentally friendly alcohol oxidation using heterogeneous catalyst in the presence of air at room temperature

被引:72
作者
Ji, HB [1 ]
Ebitani, K [1 ]
Mizugaki, T [1 ]
Kaneda, K [1 ]
机构
[1] Osaka Univ, Dept Sci & Chem Engn, Grad Sch Engn Sci, Toyonaka, Osaka 5608531, Japan
关键词
D O I
10.1016/S1566-7367(02)00194-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Various types of alcohols oxidation can be achieved using air as a sole oxidant at room temperature without any other additives. From the results of Ru K-edge XAFS and XPS characterizations, MnFe1.5Ru0.35Cu0.15O4 catalyst with possibly coordinatively unsaturation of the isolated Ru=O species as active sites is an efficient heterogeneous catalyst and can be reused. Besides, the workup procedure is extremely simple. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:511 / 517
页数:7
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