Dynamic surface tension and adsorption mechanisms of surfactants at the air-water interface

被引：763
|
作者：
Eastoe, J [1 ]
Dalton, JS [1 ]
机构：
[1] Univ Bristol, Sch Chem, Bristol BS8 7TS, Avon, England
来源：
ADVANCES IN COLLOID AND INTERFACE SCIENCE | 2000年 / 85卷 / 2-3期
基金：
英国工程与自然科学研究理事会;
关键词：
dynamic surface tension; adsorption mechanisms; surfactant adsorption;
D O I：
10.1016/S0001-8686(99)00017-2
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Recent advances in understanding dynamic surface tensions (DSTs) of surfactant solutions are discussed. For pre-CMC solutions of non-ionic surfactants, theoretical models and experimental evidence for a mixed diffusion-kinetic adsorption mechanism are covered. For micellar solutions of non-ionics, up to approximately 100 x CMC, the DST behaviour can also be accounted for using a mixed mechanism model. Finally, the first reported measurements of the dynamic surface excess Gamma(t), using the overflowing cylinder in conjunction with neutron reflection, are described. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：103 / 144
页数：42
相关论文
共 50 条
  • [31] Co-adsorption of carboxymethyl-cellulose and cationic surfactants at the air-water interface
    Trabelsi, S.
    Langevin, D.
    LANGMUIR, 2007, 23 (03) : 1248 - 1252
  • [32] Line tension of nematic pancakes at the air-water interface: Static and dynamic measurements
    Delabre, U.
    Richard, C.
    Meunier, J.
    Cazabat, A. -M.
    EPL, 2008, 83 (06)
  • [33] Surface behavior, microheterogeneity and adsorption equilibrium of myelin at the air-water interface
    Oliveira, RG
    Maggio, B
    CHEMISTRY AND PHYSICS OF LIPIDS, 2003, 122 (1-2) : 171 - 176
  • [34] Adsorption of poly(ethylene oxide) at the air/water interface:: A dynamic and static surface tension study
    Gilanyi, Tibor
    Varga, Imre
    Gilanyi, Magdolna
    Meszaros, Robert
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2006, 301 (02) : 428 - 435
  • [35] Vibration spectroscopy of surfactants in solution and at the air-water interface
    Fina, LJ
    SURFACTANT ADSORPTION AND SURFACE SOLUBILIZATION, 1995, 615 : 316 - 341
  • [36] Mixed monolayers of polyelectrolytes and surfactants at the air-water interface
    Asnacios, A
    Klitzing, R
    Langevin, D
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2000, 167 (1-2) : 189 - 197
  • [37] Merging of two droplets at an air-water interface driven by surface tension gradient
    Panday, Prashant Narayan
    Darshan, Shreyansh
    Bandopadhyay, Aditya
    Das, Prasanta Kumar
    CHEMICAL ENGINEERING SCIENCE, 2024, 288
  • [38] ENERGETICS OF SURFACTANT ADSORPTION AT AIR-WATER INTERFACE
    MANKOWICH, AM
    JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1966, 43 (11) : 615 - +
  • [39] Dynamic surface tension and adsorption kinetics of β-casein at the solution air interface
    Miller, R
    Fainerman, VB
    Aksenenko, EV
    Leser, ME
    Michel, M
    LANGMUIR, 2004, 20 (03) : 771 - 777
  • [40] Adsorption kinetics of diazinon at the air-water interface
    Lin, SY
    Lin, LW
    Chang, HC
    Ku, Y
    JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (41): : 16678 - 16684
12345