Dynamic surface tension and adsorption mechanisms of surfactants at the air-water interface

被引：764
|
作者：
Eastoe, J [1 ]
Dalton, JS [1 ]
机构：
[1] Univ Bristol, Sch Chem, Bristol BS8 7TS, Avon, England
来源：
ADVANCES IN COLLOID AND INTERFACE SCIENCE | 2000年 / 85卷 / 2-3期
基金：
英国工程与自然科学研究理事会;
关键词：
dynamic surface tension; adsorption mechanisms; surfactant adsorption;
D O I：
10.1016/S0001-8686(99)00017-2
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Recent advances in understanding dynamic surface tensions (DSTs) of surfactant solutions are discussed. For pre-CMC solutions of non-ionic surfactants, theoretical models and experimental evidence for a mixed diffusion-kinetic adsorption mechanism are covered. For micellar solutions of non-ionics, up to approximately 100 x CMC, the DST behaviour can also be accounted for using a mixed mechanism model. Finally, the first reported measurements of the dynamic surface excess Gamma(t), using the overflowing cylinder in conjunction with neutron reflection, are described. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：103 / 144
页数：42
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