Highly efficient antifouling ultrafiltration membranes incorporating zwitterionic poly([3-(methacryloylamino)propyl]-dimethyl(3-sulfopropyl) ammonium hydroxide)

被引：63

作者：

Wang, Lijun ^{[1
]}

Su, Yan-lei ^{[1
]}

Zheng, Lili ^{[1
]}

Chen, Wenjuan ^{[1
]}

Jiang, Zhongyi ^{[1
]}

机构：

[1] Tianjin Univ, Sch Chem Engn & Technol, Minist Educ, Key Lab Green Technol, Tianjin 300072, Peoples R China

来源：

JOURNAL OF MEMBRANE SCIENCE | 2009年 / 340卷 / 1-2期

基金：

国家教育部博士点专项基金资助;

关键词：

Zwitterionic membrane; Protein; Ultrafiltration; Antifouling; TRANSFER RADICAL POLYMERIZATION; PROTEIN ADSORPTION; SULFOBETAINE POLYMERS; PHOSPHOLIPID POLYMERS; SURFACE; PHOSPHORYLCHOLINE; COPOLYMER; PROPERTY; POLYZWITTERIONS; ACRYLONITRILE;

D O I：

10.1016/j.memsci.2009.05.027

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

A novel membrane material based on random copolymer composed of poly(acrylonitrile-([3(methacryloylamino)propyl]-dimethyl(3-sulfopropyl) ammonium hydroxide)) (PAN-MPDSAH) was synthesized by the water phase suspension polymerization. The zwitterionic PAN-based membranes were prepared through blending PAN and PAN-MPDSAH copolymer by a phase inversion method. The zwitterionic PAN-based membranes have higher hydrophilicity and wettability, and lower protein adsorption in comparison with the control PAN membrane. Ultrafiltration experiments revealed that membrane fouling, especially irreversible membrane fouling, for the zwitterionic PAN-based membranes is remarkably reduced due to the incorporation of zwitterionic PMPDSAH segments on the membrane surfaces. Moreover, the reversible membrane fouling during ultrafiltration process can be easily washed away by simple water cleaning. The zwitterionic PAN-based membranes can run for a long time and be reused without significant decrease of separation performance. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：164 / 170

页数：7

共 39 条

[1] Anti-fouling ultrafiltration membranes containing polyacrylonitrile-graft-poly (ethylene oxide) comb copolymer additives [J].